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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bini, Marcella
University of Pavia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Hydroxyapatite Nanorods Based Drug Delivery Systems for Bumetanide and Meloxicam, Poorly Water Soluble Active Principlescitations
- 2024Effect of Mn Substitution on GeFe2O4 as an Anode for Sodium Ion Batteriescitations
- 2024Pure and (Sn or Mg) Doped GeFe2O4 as Anodes for Sodium-Ion Batteries
- 2023Hybrid Nanocomposites of Tenoxicam: Layered Double Hydroxides (LDHs) vs. Hydroxyapatite (HAP) Inorganic Carrierscitations
- 2023Understanding the electrochemical features of ZnFe2O4, anode for LIBs, by deepening its physico-chemical propertiescitations
- 2021Synergistic Effect of Polymorphs in Doped NaNi0.5Mn0.5O2 Cathode Material for Improving Electrochemical Performances in Na-Batteriescitations
- 2018Layered Double Hydroxides (LDHs): Versatile and Powerful Hosts for Different Applicationscitations
- 2016New materials for Li-ion batteries: Synthesis and spectroscopic characterization of Li2(FeMnCo)SiO4 cathode materialscitations
- 2016New materials for Li-ion batteries : synthesis and spectroscopic characterization of Li2(FeMnCo) SiO4 cathode materialscitations
- 2014Fabrication and electrochemical characterization of amorphous lithium iron silicate thin films as positive electrodes for lithium batteriescitations
- 2013Polymorphism and magnetic properties of Li2MSiO4 (M = Fe, Mn) cathode materialscitations
- 2013Polymorphism and magnetic properties of Li2MSiO4 (M = Fe, Mn) cathode materialcitations
- 2011Bone reconstruction: Au nanocomposite bioglasses with antibacterial propertiescitations
- 2010Phase stability and homogeneity in undoped and Mn-doped LiFePO4 under laser heatingcitations
- 2009SiO2-P2O5-CaO glasses and glass-ceramics with and without ZnO: relationships among composition, microstructure, and bioactivitycitations
- 2004Role of doping and CuO segregation in improving the giant permittivity of CaCu3Ti4O12
- 2004New remarks on the high-polarizability perovskite-related material CaCu3Ti4O12citations
- 2004Electric and dielectric properties of pure and doped CaCu3Ti4O12 perovskite materials.
- 2000Magnetic investigation of Mn ions in La,Mn:SrTiO3citations
Places of action
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article
Synergistic Effect of Polymorphs in Doped NaNi0.5Mn0.5O2 Cathode Material for Improving Electrochemical Performances in Na-Batteries
Abstract
Layered NaNi0.5Mn0.5O2, employed as cathode materials in sodium ion batteries, is attracting interest due to its high working potential and high-capacity values, thanks to the big sodium amount hosted in the lattice. Many issues are, however, related to their use, particularly, the complex phase transitions occurring during sodium intercalation/deintercalation, detrimental for the structure stability, and the possible Mn dissolution into the electrolyte. In this paper, the doping with Ti, V, and Cu ions (10% atoms with respect to Ni/Mn amount) was used to stabilize different polymorphs or mixtures of them with the aim to improve the capacity values and cells cyclability. The phases were identified and quantified by means of X-ray powder diffraction with Rietveld structural refinements. Complex voltammograms with broad peaks, due to multiple structural transitions, were disclosed for most of the samples. Ti-doped sample has, in general, the best performances with the highest capacity values (120 mAh/g at C/10), however, at higher currents (1C), Cu-substituted sample also has stable and comparable capacity values.