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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Krok, Franciszek
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Functionalization of polypropylene by TiO$_{2}$ photocatalytic nanoparticles : on the importance of the surface oxygen plasma treatmentcitations
- 2024Transition to metallic and superconducting states induced by thermalor electrical deoxidation of the dislocation network in the surface regionof SrTiO3
- 2023Atomic-scale characterization of contact interfaces between thermally self-assembled Au islands and few-layer MoS2 surfaces on SiO2citations
- 2023Heterogeneity in La distribution in highly La-doped SrTiO$_{3}$ crystalscitations
- 2023Annihilation and generation of dislocations by irradiation by ions and electrons in strontium titanate single crystalcitations
- 2023The Effect of Reduction and Oxidation Processes on the Work Function of Metal Oxide Crystals: TiO2(110) and SrTiO3(001) Casecitations
- 2021Into the origin of electrical conductivity for the metal–semiconductor junction at the atomic levelcitations
- 2020Localized electrochemical redox reactions in yttria-stabilized zirconia single crystalscitations
- 2020Localized electrochemical redox reactions in yttria-stabilized zirconia single crystalscitations
- 2019Kelvin probe force microscopy work function characterization of transition metal oxide crystals under ongoing reduction and oxidationcitations
- 2018Thermally controlled growth of surface nanostructures on ion-modified AIII-BV semiconductor crystalscitations
- 2017Status report on high temperature fuel cells in Poland – Recent advances and achievementscitations
- 2017Retrieving the quantitative chemical information at nanoscale from scanning electron microscope energy dispersive x-ray measurements by machine learningcitations
- 2016Dynamics of thermally induced assembly of Au nanoislands from a thin Au layer on Ge(001)citations
- 2015Study of ageing effects in polymer-in-salt electrolytes based on poly(acrylonitrile-co-butyl acrylate) and lithium saltscitations
- 2012Multi-probe characterization of 1D and 2D nanostructures assembled on Ge(001) surface by gold atom deposition and annealingcitations
- 2006Structural and transport properties of LiFe<inf>0.45</inf>Mn<inf>0.55</inf>PO<inf>4</inf> as a cathode material in Li-ion batteries
- 2003Effects of inhomogeneity on ionic conductivity and relaxations in PEO and PEO–salt complexescitations
Places of action
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article
The Effect of Reduction and Oxidation Processes on the Work Function of Metal Oxide Crystals: TiO2(110) and SrTiO3(001) Case
Abstract
<jats:p>The strict control of the work function of transition metal oxide crystals is of the utmost importance not only to fundamental research but also to applications based on these materials. Transition metal oxides are highly abundant in electronic devices, as their properties can be easily modified using redox processes. However, this ease of tuning is a double-edged sword. With the ease of manipulation comes difficulty in controlling the corresponding process. In this study, we demonstrate how redox processes can be induced in a laboratory setting and how they affect the work function of two model transition metal oxide crystals, namely titanium dioxide TiO2(110) and strontium titanate SrTiO3(001). To accomplish this task, we utilized Kelvin Probe Force Microscopy (KPFM) to monitor changes in work function, Scanning Tunneling Microscopy (STM), and Low-Energy Electron Diffraction (LEED) to check the surface morphology and reconstruction, and we also used X-ray Photoelectron Spectroscopy (XPS) to determine how the surface composition evolves. We also show that using redox processes, the work function of titanium dioxide can be modified in the range of 3.4–5.0 eV, and that of strontium titanate can be modified in the range of 2.9–4.5 eV. Moreover, we show that the presence of an oxygen-gaining material in the vicinity of a transition metal oxide during annealing can deepen the changes to its stoichiometry and therefore the work function.</jats:p>