| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Shova, Sergiu
Institute of Macromolecular Chemistry
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Crystal structure of a water oxidation catalyst solvate with composition (NH4)2[FeIV(L-6H)]·3CH3COOH (L = clathrochelate ligand)citations
- 2023A Manganese(II) 3D Metal–Organic Framework with Siloxane-Spaced Dicarboxylic Ligand: Synthesis, Structure, and Propertiescitations
- 2022New Cyanido-Bridged Complexes of Zn(II) and/or Ag(I) with TPymT and Tptz Ligands: Synthesis, Structural and Fluorescent Propertiescitations
- 2021Synthesis and Characterisation of New {Fe2CrO} Heterotrinuclear Iron-chromium Clusters
- 2021Coumarin-Based Triapine Derivatives and Their Copper(II) Complexes: Synthesis, Cytotoxicity and mR2 RNR Inhibition Activitycitations
- 2020Electrically driven artificial muscles using novel polysiloxane elastomers modified with nitroaniline push-pull moietiescitations
- 2020Nanoscale Coordination Polymer of Dimanganese(II) as Infinite, Flexible Nanosheets with Photo‐Switchable Morphologycitations
- 2018Synthesis of novel cyclosiloxane monomers containing push–pull moieties and their anionic ring opening polymerizationcitations
- 2016Does the sign of the Cu–Gd magnetic interaction depend on the number of atoms in the bridge?citations
Places of action
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article
New Cyanido-Bridged Complexes of Zn(II) and/or Ag(I) with TPymT and Tptz Ligands: Synthesis, Structural and Fluorescent Properties
Abstract
<jats:p>The use of two triazine-derived pincer ligands led to the obtaining of a heterometallic compound and of an unexpected 3D coordination polymer (CP). Therefore, by reacting 2,4,6-tri(2-pyridyl)-1,3,5-triazine (tptz) with Zn(NO3)2 and K[Ag(CN)2], the cyanido-bridged [Ag(CN)(m-CN)]2[Zn(tptz)(H2O)] (1) trinuclear complex was formed. Compound 1 crystallizes in the orthorhombic polar space group Aea2 and the crystal packing involves argentophilic interactions. When 2,4,6-Tris(2-pyrimidyl)-1,3,5-triazine (TPymT) was used as a ligand, along with the same precursors as for 1, a 3D CP was assembled, [Ag6(CN)6(TPymT)2] (2). The formation of 2 was favored, most likely, by the dicyanoargentate(I) ion dissociation and its interesting topology is due to the bridging cyanide ligands and argentophilic interactions. The fluorescence of both compounds was studied and compared to the emission features of their ligands. For the two coordination compounds, ligand-centered fluorescence data are discussed.</jats:p>