| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Yahia, Hamdi Ben
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO2 and Methane Capturecitations
- 2022Cyclohexylammonium Hexaisothiocyanatonickelate(II) Dihydrate as a Single-Source Precursor for High Surface Area Nickel Oxide and Sulfide Nanocrystalscitations
- 2016Crystal structure of the alluaudite Ag<sub>2</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub>citations
- 2014The new disordered triplite polymorph of Co<sub>2</sub>[PO<sub>4</sub>]F
- 2011The Solid Solution Lu<sub>2–x</sub>Sc<sub>x</sub>SiO<sub>5</sub>citations
- 2010Condensed [OPr<sub>4</sub>]<sup>10+</sup> and Discrete [AsO<sub>3</sub>]<sup>3–Ψ1</sup>-Tetrahedra in Pr<sub>5</sub>O<sub>4</sub>Cl[AsO<sub>3</sub>]<sub>2</sub>citations
- 2010Intermetallic Magnesium Compounds RE<sub>2</sub>Ni<sub>2</sub>Mg<sub>3</sub> (RE =Gd, Dy–Tm, Lu) with Tb<sub>2</sub>Ni<sub>2</sub>Mg<sub>3</sub>-type Structurecitations
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article
Cyclohexylammonium Hexaisothiocyanatonickelate(II) Dihydrate as a Single-Source Precursor for High Surface Area Nickel Oxide and Sulfide Nanocrystals
Abstract
<jats:p>Cyclohexylammonium hexaisothiocyanatonickelate(II) dihydrate, (C6H11NH3)4[Ni(NCS)6]·2H2O, was synthesized, for the first time, by a four-step method in a yield of 95%. The compound was fully characterized by elemental microanalysis, Fourier transform infrared (FTIR), ultraviolet-visible-near infrared (UV-Vis-NIR), and nuclear magnetic resonance (NMR) spectroscopy and thermogravimetry. A single crystal X-ray diffraction (SXRD) gave the monoclinic space group P21/c with a = 15.8179 (5) Å, b = 10.6222 (3) Å, c = 13.8751 (4) Å, β = 109.362 (1)°, V = 2199.45 (11) Å3, Z = 2 (T = 293 K) for this novel hybrid organic–inorganic compound. The title compound was employed as a single-source precursor for the synthesis of mesoporous, high surface area nickel oxide (53 Å; 452 m2/g) and nickel sulfide (46 Å; 220 m2/g) via pyrolysis under air at 550 °C or helium atmosphere at 500 °C, respectively. X-ray powder diffraction (XRPD) demonstrated the nanocrystalline nature of both NiO and NiS with an average crystallite size of 16 and 54 nm, respectively. Scanning electron microscope (SEM) indicated the formation of agglomerated, quasi-spherical particles of nickel oxide and agglomerated flake-like structures of nickel sulfide. The high surface area, porosity, and nanocrystallinity of both NiO and NiS, obtained via this approach, are promising for a wide spectrum of applications.</jats:p>