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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mošner, Petr
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024A significant enhancement of sodium ion conductivity in phosphate glasses by addition of WO3 and MoO3: the effect of mixed conventional–conditional glass-forming oxidescitations
- 2024The influence of B2O3 on structure and ionic conductivity of lithium phosphate-niobate glassescitations
- 2023Glass structure as a driver of polaronic conductivity in phosphate glasses containing MoO<sub>3</sub> and WO<sub>3</sub>citations
- 2022Sodium-Ion Conductivity and Humidity-Sensing Properties of Na2O-MoO3-P2O5 Glass-Ceramics ; Iontová vodivost sodíku a sensorové vlastnosti vůči vlhkosti sklokeramiky Na2O-MoO3-P2O5citations
- 2022Structure-Property Correlation in Sodium Borophosphate Glasses Modified with Niobium Oxidecitations
- 2021A significant enhancement of sodium ion conductivity in phosphate glasses by addition of WO<sub>3</sub> and MoO<sub>3</sub>: the effect of mixed conventional–conditional glass-forming oxidescitations
- 2020High Electronically Conductive Tungsten Phosphate Glass-Ceramicscitations
- 2019Scaling features of conductivity spectra reveal complexities in ionic, polaronic and mixed ionic-polaronic conduction in phosphate glassescitations
- 2016Structural investigation of BaO-B2O3-P2O5 glasses by NMR and Raman spectroscopy ; Studium struktury skel BaO-B2O3-P2O5 glasses NMR and Ramanovou spektroskopiícitations
- 2016Structural investigation of BaOB2O3P2O5 glasses by NMR and Raman spectroscopycitations
- 2016Structure–property relationships in barium borophosphate glasses modified with niobium oxidecitations
- 2016Insertion of MoO3 in Borophosphate Glasses Investigated by Magnetic Resonance Spectroscopies ; Studium vlivu přídavku MoO3 na strukturu borofosforečnanových skel pomocí pokročilých metod NMRcitations
- 2016Structure-property relationships in barium borophosphate glasses modified with niobium oxide ; Relace struktura-vlastnosti v borofosfátových sklech barnatých modifikovaných oxidem niobičnýmcitations
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article
Structure-Property Correlation in Sodium Borophosphate Glasses Modified with Niobium Oxide
Abstract
International audience ; Bulk glasses of the series (100−x)[0.4Na2O-0.2Nb2O5-0.4P2O5]-xB2O3 with x = 0–48 mol% B2O3 were prepared by slow cooling in air. Their glass transition temperature increases within the range of 0–16 mol% B2O3, but further additions of B2O3 result in its decrease. Their structure was investigated by Raman, 11B, and 31P MAS NMR spectroscopy. The relative number of BO4 units decreases with increasing B2O3 content, while the number of BO3 units increases up to 59 % at x = 48. The upfield shift of a broad resonance peak in the 31P MAS NMR spectra is ascribed to an increasing connectedness of the structural network with increasing B2O3 content. Strong Raman band at 916–929 cm−1 shows on the presence of NbO6 octahedra in the structural network of these glasses. With the B2O3 addition, a decrease in DC conductivity is observed, which is attributed to the decrease in the concentration of Na+ ions.