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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gentile, Luigi
University of Bari Aldo Moro
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (5/5 displayed)
- 2023Preparation of Laser-Ablated Ag Nanoparticle–MMT Clay-Based Beeswax Antibiofilm Coatingcitations
- 2022Biobased Approach for Synthesis of Polymers and Sustainable Formulation of Industrial Hardenerscitations
- 2022Understanding the self-assembly of the polymeric drug solubilizer Soluplus®citations
- 2020Comparison of small‐angle neutron and X‐ray scattering for studying cortical bone nanostructurecitations
- 2017Non-Lamellar lipid assembly at interfaces : Controlling layer structure by responsive nanogel particlescitations
Places of action
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article
Biobased Approach for Synthesis of Polymers and Sustainable Formulation of Industrial Hardeners
Abstract
<jats:p>The adhesive manufacturing industry needs more eco-sustainable processes. In this regard, the main road is to replace raw fossil materials with renewable resources or waste biomass, and simultaneously improve synthetic steps by using clean and greener reagents under mild conditions. In this paper, a synthetic pathway for producing biobased succinyl peroxide (SP) from waste biomass is reported, and then the application range of this polymerization agent to methacrylates and styrene-free resins is extended. At the same time, new formulations of pastes based on benzoyl or succinyl peroxide, displaying an almost complete biobased carbon content, are investigated and tested as cross-linking agents for mastic marble and unsaturated polyester resins. Physicochemical characterization of the final products and polymers is carried out with thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR), Gel Permeation Chromatography (GPC), Nuclear Magnetic Resonance (NMR) and peak exothermic curve analyses.</jats:p>