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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kovacheva, Daniela
Institute of General and Inorganic Chemistry
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 20253D Printed Ni–Cu Sodalite Catalysts for Sustainable γ-Valerolactone Production from Levulinic Acid—Effect of the Copper Content and the Method of Preparation
- 2024The Formation of γ-Valerolactone from Renewable Levulinic Acid over Ni-Cu Fly Ash Zeolite Catalystscitations
- 2024Unveiling the synergistic effects of pH and Sn content for tuning the catalytic performance of Ni^0/Ni_{x}Sn_{y} intermetallic compounds dispersed on Ce-Zr mixed oxides in the aqueous phase reforming of ethylene glycol
- 2022Synthesis and characterization of nanosized ZnFe2O4 powders obtained by sonochemistry
- 2021Magneto-optical characterization of ZnO / Ni nano-laminate obtained via Atomic Layer Depositioncitations
- 2021Effect of the Post-Deposition Thermal Treatment on the Mechanical Properties of a Compositionally Modulated CrAlSiN-AlSiN Coatingcitations
- 2021Rietveld Study of the Changes of Phase Composition, Crystal Structure, and Morphology of BiFeO3 by Partial Substitution of Bismuth with Rare-Earth Ionscitations
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article
Effect of the Post-Deposition Thermal Treatment on the Mechanical Properties of a Compositionally Modulated CrAlSiN-AlSiN Coating
Abstract
<jats:p>A CrAlSiN-AlSiN coating with periodically modulated composition was investigated regarding dependence of the mechanical properties and toughness, morphology, composition, and structure on thermal treatment in the interval of 600–900 °C in argon ambience. The coating exhibited superhardness and high toughness up to 800 °C. A very slight decrease in the nanohardness, resistance to elastic strain to failure, and plastic deformation were observed. The coating had enhanced elastic recovery stable up to 700 °C. It was found that the coating morphology was not substantially influenced by the thermal treatment. X-ray diffraction (XRD) analysis revealed that the modulated coating had a nanocomposite structure, which did not change after annealing, even at 900 °C. The grains were composed mainly of fcc-CrN and h-AlN phases embedded into an amorphous Si3N4 matrix. A small amount of an h-Cr2N phase appeared after heating at temperatures above 700 °C. The coating composition was examined by energy-dispersive X-ray spectroscopy (EDS). The coating was stoichiometric up to 800 °C. It became sub-stoichiometric with respect to nitrogen after annealing at 800 °C and 900 °C. It is thus concluded that the CrAlSiN-AlSiN coating with a periodically modulated structure keeps the combination of superhardness (45.3 GPa) and improved toughness (H3/E*2 = 0.362 GPa, elastic recovery 57%) at temperatures up to 800 °C, and is suitable for high thermal applications.</jats:p>