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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ojha, Nirajan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2021Preparation of glass-based composites with green upconversion and persistent luminescence using modified direct doping methodcitations
- 2021Tailoring the glass composition to increase the thermal stability without impacting the crystallization behavior of oxyfluorophosphate glasscitations
- 2020Effect of heat-treatment on the upconversion of NaYF4:Yb3+, Er3+ nanocrystals containing silver phosphate glasscitations
- 2020Nucleation and growth behavior of Er3+doped oxyfluorophosphate glassescitations
- 2020Investigation of Upconversion Properties from Active Crystals in Oxyfluorophosphate Glasses
- 2019Phosphate glasses with blue persistent luminescence prepared using the direct doping methodcitations
- 2019Fabrication and characterization of new phosphate glasses and glass-ceramics suitable for drawing optical and biophotonic fibers
- 2019Sintered silica bodies with persistent luminescencecitations
- 2019Spectroscopic properties of Er3+-doped particles-containing phosphate glasses fabricated using the direct doping methodcitations
- 2019Spectroscopic properties of Er3+ -doped particles-containing phosphate glasses fabricated using the direct doping methodcitations
- 2018Influence of the phosphate glass melt on the corrosion of functional particles occurring during the preparation of glass-ceramicscitations
- 2018Decomposition of persistent luminescent microparticles in corrosive phosphate glass meltcitations
- 2016Borosilicate glass with enhanced hot forming properties and conversion to hydroxyapatite
Places of action
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article
Tailoring the glass composition to increase the thermal stability without impacting the crystallization behavior of oxyfluorophosphate glass
Abstract
International audience ; Even though the (75 NaPO3-25 CaF2) (in mol%) glass can be heat-treated into transparent glass-ceramic with Er3+ doped CaF2 crystals precipitating in the volume of the glass during heat-treatment, this glass was found to be a poor glass former, limiting its use as upconverter under 975 nm pumping. In this study, the impact of the glass composition on the thermal, optical and structural properties of the glass was investigated in order to understand how the glass composition can be tailored for the development of thermally stable upconverter glass-based material. The addition of MgO, Fe2O3 and Al2O3 in the NaPO3-CaF2 glass system increases the thermal stability of glass due to the depolymerization of the glass network. However, the changes in the glass composition also impacted on the nucleation and growth process. Indeed, CaF2 and other crystals were found in the newly developed glasses after heat-treatment leading to glass-ceramics with lower intensity of upconversion than the (75 NaPO3-25 CaF2) glass-ceramic used as a reference. Glasses were also prepared with different concentrations of Er2O3 and ErF3. These glasses were found to be promising as not only are they thermally stable, but they also exhibit green and red emission with high intensity under 975 nm pumping due to Er3+ clustering.