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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Belo, Jh
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Highly Efficient and Magnetically Recyclable Non-Noble Metal Fly Ash-Based Catalysts for 4-Nitrophenol Reductioncitations
- 2023Tunable Iron–Cobalt Thin Films Grown by Electrodepositioncitations
- 2023Magnetic polylactic acid-calcium phosphate-based biocomposite as a potential biomaterial for tissue engineering applicationscitations
- 2023Design and photo-Fenton performance of Graphene/CuS/Fe3O4 tertiary nanocomposites for Rhodamine B degradationcitations
- 2022Indium segregation in Gd-5(Si, Ge)(4) magnetocaloric materialscitations
- 2022Magnetoresponsive Optical Fiber with Fuse-Effect-Induced Fluorinated Graphene Oxide Corecitations
- 2020Freestanding and flexible composites of magnetocaloric Gd-5(Si,Ge)(4) microparticles embedded in thermoplastic poly(methyl methacrylate) matrixcitations
- 2019Multicaloric effect in a multiferroic composite of Gd-5(Si,Ge)(4) microparticles embedded into a ferroelectric PVDF matrixcitations
- 2018Lanthanum Dilution Effects on the Giant Magnetocaloric Gd5Si1.8Ge2.2 Compoundcitations
- 2017Suppression of magnetostructural transition on GdSiGe thin film after thermal cyclingscitations
- 2017On the nature of the (de)coupling of the magnetostructural transition in Er5Si4citations
- 2015On the growth and physical-chemical characterization of Tb5Si2Ge2 thin films produced by electron-beam evaporationcitations
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article
Highly Efficient and Magnetically Recyclable Non-Noble Metal Fly Ash-Based Catalysts for 4-Nitrophenol Reduction
Abstract
4-nitrophenol (4-NPh) is a harmful compound produced in large amounts in the chemical industry, and its reduction to aminophenol (4-APh) using noble metals as catalysts is one of the most studied processes. The development of noble metal-free catalysts represents an economic advantage in large-scale applications and contributes to the sustainability of raw materials. Coal fly ash (FA), a major waste stream from coal combustion, contains an easily recoverable magnetic fraction (FAmag sample) composed of Fe-rich particles that could substitute noble metal catalysts in 4-NPh reduction, with the concomitant advantage of being easily recovered via magnetic separation. For this purpose, a new composite material containing copper ferrite nanoparticles (FAmag@CS@CuFe) was prepared via a facile, environmentally friendly and cost-effective method based on three components: FAmag as the core, a biobased polymer chitosan (CS) as the linker and copper ferrite CuFe2O4 nanoparticles (CuFe) as the active sites. The structure, morphology, composition and magnetic properties of the FAmag@CS@CuFe material were studied to assess the efficiency of the preparation. It was found that the biopolymer prevented the aggregation of CuFe nanoparticles and enabled a synergistically outstanding activity towards the reduction of 4-NPh in comparison to the pristine FAmag and bare CuFe nanoparticles. The FAmag@CS@CuFe catalyst showed efficiency and stability in the conversion of 4-NPh of up to 95% in 3 min over four consecutive cycles. Such remarkable catalytic results demonstrate the potential of this catalyst as a substitute for expensive noble metals.