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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Østergaard, Martin Bonderup
Aalborg University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2024Anomaly in the relation between thermal conductivity and crystallinity of silicate glass-ceramicscitations
- 2024Suppressing the thermal conduction in glass–ceramic foams by controlling crystallizationcitations
- 2024Crystallinity dependence of thermal and mechanical properties of glass-ceramic foamscitations
- 2024A self-cleaning thermocatalytic membrane for bisphenol a abatement and fouling removalcitations
- 2023A Thermocatalytic Ceramic Membrane by Perovskite Incorporation in the Alumina Frameworkcitations
- 2023Thermocatalytic Performance of LaCo1−xNixO3−δ Perovskites in the Degradation of Rhodamine Bcitations
- 2023Beneficial effect of cerium excess on in situ grown Sr0.86Ce0.14FeO3–CeO2 thermocatalysts for the degradation of bisphenol Acitations
- 2023Beneficial effect of cerium excess on in situ grown Sr 0.86 Ce 0.14 FeO 3 –CeO 2 thermocatalysts for the degradation of bisphenol Acitations
- 2022Fracture energy of high-Poisson’s ratio oxide glassescitations
- 2021The foaming mechanism of glass foams prepared from the mixture of Mn 3 O 4 , carbon and CRT panel glasscitations
- 2021The foaming mechanism of glass foams prepared from the mixture of Mn3O4, carbon and CRT panel glasscitations
- 2021Degradation of organic micropollutants in water using a novel thermocatalytic membrane
- 2020Structure Dependence of Poisson’s Ratio in Cesium Silicate and Borate Glassescitations
- 2019Revisiting the Dependence of Poisson’s Ratio on Liquid Fragility and Atomic Packing Density in Oxide Glassescitations
- 2018Effect of alkali phosphate content on foaming of CRT panel glass using Mn3O4 and carbon as foaming agentscitations
- 2017Influence of foaming agents on solid thermal conductivity of foam glasses prepared from CRT panel glasscitations
- 2017Thermal Conductivity of Foam Glasses Prepared using High Pressure Sintering
- 2017Foaming Glass Using High Pressure Sintering
- 2016Influence of foaming agents on both the structure and the thermal conductivity of silicate glasses
Places of action
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article
Thermocatalytic Performance of LaCo1−xNixO3−δ Perovskites in the Degradation of Rhodamine B
Abstract
Perovskite-type LaCo1−xNixO3−δ (x = 0, 0.2, 0.4, 0.6, and 0.8) powders were synthesized by solution combustion synthesis. The crystal structure, morphology, texture, and surface were characterized by X-ray powder diffraction combined with Rietveld refinement, scanning electron microscopy, N2-adsorption, X-ray photoelectron spectroscopy, and zeta-potential analysis. The thermocatalytic properties of the perovskites were investigated by UV–Vis spectroscopy through degradation of rhodamine B in the temperature range 25–60 °C. For the first time, this perovskite system was proven to catalyze the degradation of a water pollutant, as the degradation of rhodamine B occurred within 60 min at 25 °C. It was found that undoped LaCoO3−δ is the fastest to degrade rhodamine B, despite exhibiting the largest energy band gap (1.90 eV) and very small surface area (3.31 m2 g−1). Among the Ni-doped samples, the catalytic performance is balanced between two main contrasting factors, the positive effect of the increase in the surface area (maximum of 12.87 m2 g−1 for 80 mol% Ni) and the negative effect of the Co(III) stabilization in the structure (78% in LaCoO3 and 89–90% in the Ni-containing ones). Thus, the Co(II)/Co(III) redox couple is the key parameter in the dark ambient degradation of rhodamine B using cobaltite perovskites.