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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Valášková, Marta
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2022Hematites Precipitated in Alkaline Precursors: Comparison of Structural and Textural Properties for Methane Oxidationcitations
- 2021Photocatalytic water splitting over CeO2/Fe2O3/Ver photocatalystscitations
- 2020Magnesium Effect in K/Co-Mg-Mn-Al Mixed Oxide Catalyst for Direct NO Decompositioncitations
- 2018Graphite an exfoliated and organomodified filler for polymeric nanocomposites
- 2014Cobalt-organovermiculite arrangement and mechanical properties: models and experiments
- 2014Structural characteristics of cordierite/steatite ceramics sintered from mixtures containing pore-forming organovermiculitecitations
- 2014Antibacterial efficiency of vermiculite/chlorhexidine nanocomposites and results of the in vivo test of harmlessness of vermiculitecitations
- 2014Antibacterial kaolinite/urea/chlorhexidine nanocomposites: Experiment and molecular modellingcitations
- 2013Role of vermiculite and zirconium-vermiculite on the formation of zircon-cordierite nanocompositescitations
- 2010Vermiculite filler for polymeric nanocomposites: thermal and dispersion study
- 2009Preparation and characterization of porous cordierite for potential use in cellular ceramicscitations
- 2008Silver nanoparticles/montmorillonite composites prepared using nitrating reagent at water and glycerolcitations
- 2007Structural ordering of organovermiculite: Experiments and modelingcitations
- 2006Structure–activity relationship in the N2O decomposition over Ni-(Mg)-Al and Ni-(Mg)-Mn mixed oxides prepared from hydrotalcite-like precursorscitations
- 2006Identification of carbon forms and other phases in automotive brake composites using multiple analytical techniquescitations
- 2006Structure of montmorillonite cointercalated with stearic acid and octadecylamine : modeling, diffraction, IR spectroscopycitations
- 2004Influence of chain length on intercalation process of polyvinylchloride/clay nanocomposites based on alkyl-aminecitations
- 2004Study of the catalytic activity of calcined Ni/Mg/Al (Mn) hydrotalcites for N2O decomposition
- 2004Structure analysis of intercalated layer silicates: combination of molecular simulations and experimentcitations
Places of action
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article
Magnesium Effect in K/Co-Mg-Mn-Al Mixed Oxide Catalyst for Direct NO Decomposition
Abstract
<jats:p>Emission of nitric oxide represents a serious environmental problem since it contributes to the formation of acid rain and photochemical smog. Potassium-modified Co-Mn-Al mixed oxide is an effective catalyst for NO decomposition. However, there are problems related to the thermal instability of potassium species and a high content of toxic and expensive cobalt. The reported research aimed to determine whether these shortcomings can be overcome by replacing cobalt with magnesium. Therefore, a series of Co-Mg-Mn-Al mixed oxides with different Co/Mg molar ratio and promoted by various content of potassium was investigated. The catalysts were thoroughly characterized by atomic absorption spectroscopy (AAS), temperature-programmed reduction by hydrogen (TPR-H2), temperature-programmed desorption of CO2 (TPD-CO2), X-ray powder diffraction (XRD), N2 physisorption, species-resolved thermal alkali desorption (SR-TAD), and tested in direct NO decomposition with and without the addition of oxygen and water vapor. Partial substitution of magnesium for cobalt did not cause an activity decrease when the optimal molar ratio of K/Co on the normalized surface area was maintained; it means that the portion of expensive and toxic cobalt can be successfully replaced by magnesium without any decrease in catalytic activity.</jats:p>