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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Amal, Rose
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2024Triggering C‒N Coupling on Metal Oxide Nanocomposite for the Electrochemical Reduction of CO<sub>2</sub> and NO<i><sub>x</sub></i>⁻ to Formamidecitations
- 2021Integrating low-cost earth-abundant co-catalysts with encapsulated perovskite solar cells for efficient and stable overall solar water splittingcitations
- 2020Dynamic single-site polysulfide immobilization in long-range disorder Cu-MOFscitations
- 2020Tuning the Selectivity of LaNiO3 Perovskites for CO2 Hydrogenation through Potassium Substitutioncitations
- 2018Multipronged Validation of Oxalate C-C Bond Cleavage Driven by Au-TiO2 Interfacial Charge Transfer Using Operando DRIFTScitations
- 2018Electroreduction of CO2 to CO on a Mesoporous Carbon Catalyst with Progressively Removed Nitrogen Moietiescitations
- 2016Photoelectrochemical water oxidation using a Bi2MoO6/MoO3 heterojunction photoanode synthesised by hydrothermal treatment of an anodised MoO3 thin filmcitations
- 2015Z-schematic water splitting into H2 and O2 using metal sulfide as a hydrogen-evolving photocatalyst and reduced graphene oxide as a solid-state electron mediatorcitations
- 2014Interface-dependent electrochemical behavior of nanostructured manganese (IV) oxide (Mn3O4)citations
- 2012A perspective on fabricating carbon-based nanomaterials by photocatalysis and their applicationscitations
- 2011Semiconductor/reduced graphene oxide nanocomposites derived from photocatalytic reactionscitations
Places of action
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article
Tuning the Selectivity of LaNiO3 Perovskites for CO2 Hydrogenation through Potassium Substitution
Abstract
<jats:p>Herein, we demonstrate a method used to tune the selectivity of LaNiO3 (LNO) perovskite catalysts through the substitution of La with K cations. LNO perovskites were synthesised using a simple sol-gel method, which exhibited 100% selectivity towards the methanation of CO2 at all temperatures investigated. La cations were partially replaced by K cations to varying degrees via control of precursor metal concentration during synthesis. It was demonstrated that the reaction selectivity between CO2 methanation and the reverse water gas shift (rWGS) could be tuned depending on the initial amount of K substituted. Tuning the selectivity (i.e., ratio of CH4 and CO products) between these reactions has been shown to be beneficial for downstream hydrocarbon reforming, while valorizing waste CO2. Spectroscopic and temperature-controlled desorption characterizations show that K incorporation on the catalyst surface decrease the stability of C-based intermediates, promoting the desorption of CO formed via the rWGS prior to methanation.</jats:p>