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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Maniukiewicz, Waldemar
Lodz University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Role of Climatic Cycles on the Duality of Chemical and Physical Modes of Sulfate Attack in Concrete
- 2020Hydrogen Production on Cu-Ni Catalysts via the Oxy-Steam Reforming of Methanolcitations
- 2020The Catalytic Performance of Ni-Co/Beta Zeolite Catalysts in Fischer-Tropsch Synthesiscitations
- 2020The Catalytic Performance of Ni-Co/Beta Zeolite Catalysts in Fischer-Tropsch Synthesiscitations
- 2018High active and selective Ni/Ceo2 –Al2O3 and Pd–Ni/Ceo2 –Al2O3 catalysts for oxy-steam reforming of methanolcitations
- 2017The Studies of Archaeological Pottery with the Use of Selected Analytical Techniquescitations
- 2017Synthesis and Characterization of Low Loss Dielectric Ceramics Prepared from Composite of Titanate Nanosheets with Barium Ionscitations
- 2016Bimetallic Au-Cu, Au-Ni catalysts supported on MWCNTs for oxy-steam reforming of methanolcitations
- 2016Synthesis, X-ray characterization, DFT calculations and Hirshfeld surface analysis of Zn(II) and Cd(II) complexes based on isonicotinoylhydrazone ligandcitations
- 2014Improving the Ionic Conductivity of Carboxylated Nitrile Rubber/LDH Composites by Adding Imidazolium Bis(trifluoromethylsulfonyl)imide Ionic Liquidscitations
- 2014Highly selective Pd-Cu/ZnAl2O4 catalyst for hydrogen productioncitations
- 2014Effects of unmodified layered double hydroxides MgAl-LDHs with various structures on the properties of filled carboxylated acrylonitrile-butadiene rubber XNBRcitations
Places of action
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article
Hydrogen Production on Cu-Ni Catalysts via the Oxy-Steam Reforming of Methanol
Abstract
<p>In this work, bimetallic Cu-Ni catalysts supported on binary oxides containing ZnO, ZrO<sub>2</sub>, CeO<sub>2</sub> and Al<sub>2</sub>O<sub>3</sub> were investigated in hydrogen production via the oxidative steam reforming of methanol (OSRM). Their physicochemical properties were extensively studied using various methods such as BET, TPR-H<sub>2</sub>, TPD-NH<sub>3</sub>, XRD, SEM-EDS, ToF-SIMS and XPS. The reactivity measurements showed that the active phase and support composition played an important role in the activity of the catalyst in the OSRM. The most active system at higher temperatures was 30% Cu-10% Ni/CeO<sub>2</sub>·Al<sub>2</sub>O<sub>3</sub>, with high catalytic activity attributed to the Cu<sub>0.8</sub>Ni<sub>0.2</sub> alloy formation. In addition, the reactivity results showed that the most active catalyst exhibited high acidity and was easily reduced. At low temperatures, the best catalytic properties were exhibited by 30% Cu-10% Ni/ZrO<sub>2</sub>·Al<sub>2</sub>O<sub>3</sub>. The reactivity and physicochemical properties of the studied catalysts confirmed the crucial role of alloy composition on their catalytic properties in the oxy-steam reforming of methanol. The obtained results validate the possibility of using Cu-Ni catalysts for hydrogen production.</p>