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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Macphee, Donald
University of Aberdeen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2023Fairly and Rapidly Assessing Low Carbon Concrete Made with Slowly Reacting Cements
- 2020Exposed Aggregate Areas and Photocatalytic Efficiency of Photocatalytic Aggregate Mortarcitations
- 2019Photocatalytic Functionalized Aggregatecitations
- 2018The cuboid method for measurement of thermal properties of cement-based materials using the guarded heat flow metercitations
- 2017The reactivity of aluminosilicate glasses in cements - effects of Ca content on dissolution characteristics and surface precipitationcitations
- 2017An investigation of the electronic, structural and magnetic properties of the ruddlesden-popper phase Sr3RuCoO7citations
- 2016An investigation of the optical properties and water splitting potential of the coloured metallic perovskites Sr1-xBaxMoO3citations
- 2016Band structure and charge carrier dynamics in (W,N)-codoped TiO2 resolved by electrochemical impedance spectroscopy combined with UV-vis and EPR spectroscopiescitations
- 2016The Structure and Optical Properties of Sr1-xCaxMoO3citations
- 2015Properties and photochemistry of valence-induced-Ti3+ enriched (Nb,N)-codoped anatase TiO2 semiconductorscitations
- 2011A physico-chemical basis for novel cementitious binderscitations
- 2010Novel cement systems (sustainability)citations
- 2010Effect of Calcium Additions on N-A-S-H Cementitious Gelscitations
- 2010Effect on fresh C-S-H gels of the simultaneous addition of alkali and aluminiumcitations
- 2010Factors influencing colour in white Portland cements
- 2010Engineering Photocatalytic Cements: Understanding TiO2 Surface Chemistry to Control and Modulate Photocatalytic Performancescitations
- 2010Stability of synthetic calcium silicate hydrate gels in presence of alkalis, aluminum, and soluble silicacitations
- 2009Rhodamine B discolouration on TiO 2 in the cement environmentcitations
- 2009Study of the decalcification process in mortars degraded by NH4NO3 by using ultrasonic techniquescitations
Places of action
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article
Photocatalytic Functionalized Aggregate
Abstract
Engineering of effective photocatalytically active structures is of great importance as it introduces a solution for some existing air pollution problems. This can be practically achieved through the bonding of particulate photocatalysts to the surface of construction materials, such as aggregates, with a suitable stable binding agent. However, the accessibility of the photocatalytically active materials to both the air pollutants and sunlight is an essential issue which must be carefully considered when engineering such structures. Herein, different amounts of commercial TiO2 were supported on the surface of quartz sand, as an example of aggregates, with a layer of silica gel<br/>acting as a binder between the photocatalyst and the support. The thus prepared photocatalytically active aggregates were then supported on the surface of mortars to measure their performance for NOx removal. The obtained materials were characterized by electron microscopy (SEM and TEM), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), and UV-vis Absorption Spectroscopy. Very good coverage of the support’s surface with the photocatalyst was successfully achieved as the electron microscopic images showed. FTIR spectroscopy confirmed the chemical bonding, i.e., interfacial Ti–O–Si bonds, between the photocatalyst and the silica layer. The photocatalytic activities of the obtained composites were tested for photocatalytic removal of<br/>nitrogen oxides, according to the ISO standard method (ISO 22197-1). The obtained aggregate-exposed mortars have shown up to ca. four times higher photocatalytic performance towards NO removal compared to the sample in which the photocatalyst is mixed with cement, however, the nitrate selectivity can be affected by Ti–O–Si bonding.