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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Grandfils, Christian
General Electric (Finland)
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2022Subcritical Water as a Pre-Treatment of Mixed Microbial Biomass for the Extraction of Polyhydroxyalkanoatescitations
- 2022Subcritical Water as a Pre-Treatment of Mixed Microbial Biomass for the Extraction of Polyhydroxyalkanoatescitations
- 2022Protein encapsulation in mesoporous silica: influence of the mesostructured and pore wall propertiescitations
- 2022Polyhydroxyalkanoates from A Mixed Microbial Culturecitations
- 2022Polyhydroxyalkanoates from A Mixed Microbial Culture ; Extraction Optimization and Polymer Characterizationcitations
- 2021Production of medium-chain-length polyhydroxyalkanoates by Pseudomonascitations
- 2021Preparation and Characterization of Porous Scaffolds Based on Poly(3-hydroxybutyrate) and Poly(3-hydroxybutyrate-co-3-hydroxyvalerate).citations
- 2021Preparation and characterization of porous scaffolds based on poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate)citations
- 2021Preparation of poly-D,L-lactide based nanocomposites with polymer-grafted silica by melt blending: Study of molecular, morphological, and mechanical propertiescitations
- 2020Silver nanocomposites based on the bacterial fucose-rich polysaccharide secreted by Enterobacter A47 for wound dressing applications: Synthesis, characterization and in vitro bioactivitycitations
- 2019Functionalization of silica synthesized by sol-gel process with PDLLA via "grafting to" method
- 2019Optimization of Synthesis Parameters for the Production of Biphasic Calcium Phosphate Ceramics via Wet Precipitation and Sol‐Gel Processcitations
- 2019Demonstration of the adhesive properties of the medium-chain-length polyhydroxyalkanoate produced by Pseudomonas chlororaphis subsp. aurantiaca from glycerolcitations
- 2019Production of medium-chain length polyhydroxyalkanoates by Pseudomonas citronellolis grown in apple pulp wastecitations
- 2019Production of medium-chain length polyhydroxyalkanoates by Pseudomonas citronellolis grown in apple pulp wastecitations
- 2018Optimization of calcium phosphate ceramic
- 2017Production of FucoPol by Enterobacter A47 using waste tomato paste by-product as sole carbon sourcecitations
- 2017Optimization of hydroxyapatite synthesis via sol-gel process for bone reconstruction application ; Optimisation de la synthèse d'hydroxyapatite via un procédé sol-gel pour la reconstruction osseuse
- 2016Assessment of the adhesive properties of the bacterial polysaccharide FucoPolcitations
- 2015Conversion of cheese whey into a fucose- and glucuronic acid-rich extracellular polysaccharide by Enterobacter A47citations
- 2012A Novel Approach to Design Chitosan-Polyester Materials for Biomedical Applicationscitations
Places of action
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article
Subcritical Water as a Pre-Treatment of Mixed Microbial Biomass for the Extraction of Polyhydroxyalkanoates
Abstract
Polyhydroxyalkanoate (PHA) recovery from microbial cells relies on either solvent extraction (usually using halogenated solvents) and/or digestion of the non-PHA cell mass (NPCM) by the action of chemicals (e.g., hypochlorite) that raise environmental and health hazards. A greener alternative for PHA recovery, subcritical water (SBW), was evaluated as a method for the dissolution of the NPCM of a mixed microbial culture (MMC) biomass. A temperature of 150 degrees C was found as a compromise to reach NPCM solubilization while mostly preventing the degradation of the biopolymer during the procedure. Such conditions yielded a polymer with a purity of 77%. PHA purity was further improved by combining the SBW treatment with hypochlorite digestion, in which a significantly lower hypochlorite concentration (0.1%, v/v) was sufficient to achieve an overall polymer purity of 80%. During the procedure, the biopolymer suffered some depolymerization, as evidenced by the lower molecular weight (M-w) and higher polydispersity of the extracted samples. Although such changes in the biopolymer's molecular mass distribution impact its mechanical properties, impairing its utilization in most conventional plastic uses, the obtained PHA can find use in several applications, for example as additives or for the preparation of graft or block co-polymers, in which low-M-w oligomers are sought.