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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jahn, Marcus
Austrian Institute of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2024Evaluating Polyacrylic Acid as a Universal Aqueous Binder for Ni‐Rich Cathodes NMC811 and Si Anodes in Full Cell Lithium‐ion Batteriescitations
- 2022Synthesis and comparative performance study of crystalline and partially amorphous nano-sized SnS2 as anode materials for lithium-ion batteriescitations
- 2022Advanced Binders for High Performance Lithium-ion Battery Applications
- 2022Aqueous Manufacturing of Ni-rich Cathodes Using Polyacrylic Acid as Binder for Lithium-ion Batteries
- 2022Laser Structuring in Battery Production for Enhancing the Electrochemical Performance Of thick NMC 811 High Energy Electrodes
- 2021High-performance amorphous carbon coated lini0.6mn0.2co0.2o2 cathode material with improved capacity retention for lithium-ion batteriescitations
- 2019All-solid state batteries for space explorationcitations
Places of action
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article
High-performance amorphous carbon coated lini0.6mn0.2co0.2o2 cathode material with improved capacity retention for lithium-ion batteries
Abstract
<p>Coating conducting polymers onto active cathode materials has been proven to mitigate issues at high current densities stemming from the limited conducting abilities of the metal-oxides. In the present study, a carbon coating was applied onto nickel-rich NMC622 via polymerisation of furfuryl alcohol, followed by calcination, for the first time. The formation of a uniform amorphous carbon layer was observed with scanning-and transmission-electron microscopy (SEM and TEM) and X-ray photoelectron spectroscopy (XPS). The stability of the coated active material was confirmed and the electrochemical behaviour as well as the cycling stability was evaluated. The impact of the heat treatment on the electrochemical performance was studied systematically and was shown to improve cycling and high current performance alike. In-depth investigations of polymer coated samples show that the improved performance can be correlated with the calcination temperatures. In particular, a heat treatment at 400<sup>◦</sup>C leads to enhanced reversibility and capacity retention even after 400 cycles. At 10C, the discharge capacity for carbon coated NMC increases by nearly 50% compared to uncoated samples. This study clearly shows for the first time the synergetic effects of a furfuryl polymer coating and subsequent calcination leading to improved electrochemical performance of nickel-rich NMC622.</p>