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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ivanov, Evgeni
Bulgarian Academy of Sciences
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Improving Resistive Heating, Electrical and Thermal Properties of Graphene-Based Poly(Vinylidene Fluoride) Nanocomposites by Controlled 3D Printing
- 2024New Insights in the Nanomechanical Study of Carbon-Containing Nanocomposite Materials Based on High-Density Polyethylene
- 2024PVDF hybrid nanocomposites with graphene and carbon nanotubes and their thermoresistive and joule heating propertiescitations
- 2022Thermo‐Electric Properties of Poly(lactic) Acid Filled with Carbon‐Based Particles: Experimental and Simulation Studycitations
- 2022Thermal and Dielectric Properties of 3D Printed Parts Based on Polylactic Acid Filled with Carbon Nanostructurescitations
- 2022BIOPOLYMER NANOCOMPOSITES WITH GRAPHENE FOR 3D PRINTING APPLICATIONS: PROPERTIES AND SAFETY ISSUES
- 2021Tailoring the graphene oxide chemical structure and morphology as a key to polypropylene nanocomposite performancecitations
- 2020THz Spectroscopy as a Versatile Tool for Filler Distribution Diagnostics in Polymer Nanocompositescitations
- 2019PLA/Graphene/MWCNT Composites with Improved Electrical and Thermal Properties Suitable for FDM 3D Printing Applicationscitations
- 2019Effects of Graphene Nanoplatelets and Multiwall Carbon Nanotubes on the Structure and Mechanical Properties of Poly(lactic acid) Composites: A Comparative Studycitations
- 2018Tensile and Surface Mechanical Properties of Polyethersulphone (PES) and Polyvinylidene Fluoride (PVDF) Membranescitations
- 2018Morphological, Rheological and Electromagnetic Properties of Nanocarbon/Poly(lactic) Acid for 3D Printing: Solution Blending vs. Melt Mixingcitations
- 2018Influence of carbon nanotube surface treatment on resistivity and low‐frequency noise characteristics of epoxy‐based compositescitations
- 2017Influence of polymer swelling and dissolution into food simulants on the release of graphene nanoplates and carbon nanotubes from poly(lactic) acid and polypropylene composite filmscitations
- 2014Thermal and rheological characterization of antibacterial nanocomposites: Poly(amide) 6 and low-density poly(ethylene) filled with zinc oxidecitations
- 2014Thermal and rheological characterization of antibacterial nanocompositescitations
- 2014Effect of Matrix Viscosity on Rheological and Microwave Properties of Polymer Nanocomposites with Multiwall Carbon Nanotubescitations
- 2014EPR and Rheological Study of Hybrid Interfaces in Gold-Clay-Epoxy Nanocomposites.
- 2013Applied Study on Mechanics of Nanocomposites with Carbon Nanofillerscitations
- 2010Isotactic polypropylene composites reinforced with multiwall carbon nanotubes, part 2: Thermal and mechanical properties related to the structurecitations
Places of action
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article
PLA/Graphene/MWCNT Composites with Improved Electrical and Thermal Properties Suitable for FDM 3D Printing Applications
Abstract
<jats:p>In this study, the structure, electrical and thermal properties of ten polymer compositions based on polylactic acid (PLA), low-cost industrial graphene nanoplates (GNP) and multi-walled carbon nanotubes (MWCNT) in mono-filler PLA/MWCNT and PLA/GNP systems with 0–6 wt.% filler content were investigated. Filler dispersion was further improved by combining these two carbon nanofillers with different geometric shapes and aspect ratios in hybrid bi-filler nanocomposites. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Raman spectroscopy exhibited uniform dispersion of nanoparticles in a polymer matrix. The obtained results have shown that for the mono-filler systems with MWCNT or GNP, the electrical conductivity increased with decades. Moreover, a small synergistic effect was observed in the GNP/MWCNT/PLA bi-filler hybrid composites when combining GNP and CNT at a ratio of 3% GNP/3% CNT and 1.5% GNP:4.5% CNT, showing higher electrical conductivity with respect to the systems incorporating individual CNTs and GNPs at the same overall filler concentration. This improvement was attributed to the interaction between CNTs and GNPs limiting GNP aggregation and bridging adjacent graphene platelets thus, forming a more efficient network. Thermal conductivity increases with higher filler content; this effect was more pronounced for the mono-filler composites based on PLA and GNP due to the ability of graphene to better transfer the heat. Morphological analysis carried out by electron microscopy (SEM, TEM) and Raman indicated that the nanocomposites present smaller and more homogeneous filler aggregates. The well-dispersed nanofillers also lead to a microstructure which is able to better enhance the electron and heat transfer and maximize the electrical and thermal properties. The obtained composites are suitable for the production of a multifunctional filament with improved electrical and thermal properties for different fused deposition modelling (FDM) 3D printing applications and also present a low production cost, which could potentially increase the competitiveness of this promising market niche.</jats:p>