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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Volodina, Natalia
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- 2024Investigation of the Phase Composition, Structural, Mechanical, and Dielectric Properties of (1 − x)∙ZrO2-x∙CeO2 Ceramics Synthesized by the Solid-State Methodcitations
- 2023Study of the Structural, Electrical, and Mechanical Properties and Morphological Features of Y-Doped CeO2 Ceramics with Porous Structurecitations
- 2023Study of the Aid Effect of CuO-TiO2-Nb2O5 on the Dielectric and Structural Properties of Alumina Ceramicscitations
- 2023Structural, Dielectric, and Mechanical Properties of High-Content Cubic Zirconia Ceramics Obtained via Solid-State Synthesiscitations
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article
Investigation of the Phase Composition, Structural, Mechanical, and Dielectric Properties of (1 − x)∙ZrO2-x∙CeO2 Ceramics Synthesized by the Solid-State Method
Abstract
<jats:p>Ceramics based on zirconium dioxide are very important compounds for dental, implant, and structural material applications. Despite the fact that tetragonally stabilized YSZ has been well studied, the search for new compositions of zirconia-based ceramics is still in progress. The ZrO2-CeO2 system is one of the alternatives for YSZ materials, but there is conflicting experimental data on its phase composition and mechanical properties depending on the ratio of components. In this study, we investigated the phase composition, and microstructural, mechanical, and physical properties of (1 − x)∙ZrO2-x∙CeO2 (step of x = 0.05) ceramics obtained by the solid-state sintering process from micron-sized powders. For the characterization of samples, XRD, Raman spectroscopy, SEM, the Vickers Microhardness Test, and dielectric spectroscopy were implemented. The results showed that by varying the CeO2 concentration, it is possible to synthesize stable tetragonal ZrO2 at room temperature with a high microhardness HV0.05 value of ~1500, low porosity (~2.5%), and a high dielectric constant of 36. The pronounced combined effect of tetragonal phase formation, densification, and grain size reduction on the mechanical and dielectric properties of the experimental samples was investigated. Refined experimental data make it possible to synthesize high-quality zirconia–ceria ceramics for use as refractories, dispersed nuclear fuel, or solid oxide fuel cells.</jats:p>