| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Donnio, Bertrand
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2023Star-shaped Triphenylene-triazine Multi-stimuli Responsive Discotic Liquid Crystals: Synthesis, Properties and Applicationscitations
- 2023Role of lattice defects on the magnetism of gold nanoparticles irradiated with neutronscitations
- 2022Pentacoordinated Liquid Crystalline Zn(II) Complex Organized in Smectic Mesophase: Synthesis, Structural and Electrochemical Propertiescitations
- 2022Janus-Type Dendrimers Based on Highly Branched Fluorinated Chains with Tunable Self-Assembly and 19 F Nuclear Magnetic Resonance Propertiescitations
- 2020Playing with Pt II and Zn II Coordination to Obtain Luminescent Metallomesogenscitations
- 2016Chemical engineering of donor–acceptor liquid crystalline dyads and triads for the controlled nanostructuration of organic semiconductorscitations
- 2015Spin-crossover, mesomorphic and thermoelectrical properties of cobalt(II) complexes with alkylated N3-Schiff basescitations
- 2015Tailoring Anisotropic Interactions between Soft Nanospheres Using Dense Arrays of Smectic Liquid Crystal Edge Dislocationscitations
- 2012Influence of polymorphism on charge transport properties in isomers of fluorenone-based liquid crystalline semiconductorscitations
- 2011From tectons to luminescent supramolecular ionic liquid crystalscitations
- 2011Orienting the Demixion of a Diblock-copolymer Using 193 nm Interferometric Lithography for the Controlled Deposition of Nanoparticlescitations
- 2010Diethynylbenzene-Based Liquid Crystalline Semiconductor for Solution-Processable Organic Thin-Film Transistorscitations
- 2009Miscibility Between Differently-Shaped Mesogens: Structural and Morphological Study of a Phthalocyanine-Perylene Binary Systemcitations
- 2009Miscibility between differently shaped mesogens: Structural and morphological study of a phthalocyanine-perylene binary system.citations
- 2008Metal-directed columnar phase formation in tetrahedral zinc(II) and manganese(II) metallomesogenscitations
- 2008Design of Neutral Metallomesogens from 5,5-Dimethyldipyrromethane: Metal Ion Mediated Control of Folding and Hairpin Structurescitations
- 2007Liquid-crystalline complexes of 1,10-phenanthroline
- 2005Luminescent organometallic liquid crystals based on complexes of bromotricarbonyl rhenium(I)
- 2005Phenanthrolines as versatile ligands for the design of liquid-crystalline metal complexes
- 2005Nematic liquid-crystalline lanthanide complexes
- 2004Liquid-crystalline lanthanide complexes
- 2003Lanthanide complexes forming columnar mesophases
- 2003Liquid-crystalline azines formed by the rare-earth promoted decomposition of hydrazide "habbe'' ligands: structural and thermal properties (vol 13, pg 1639, 2003)
- 2003The search for nematic lanthanide mesogens: a surprising outcome
- 2002Mixed copper - lanthanide metallomesogenscitations
Places of action
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article
Pentacoordinated Liquid Crystalline Zn(II) Complex Organized in Smectic Mesophase: Synthesis, Structural and Electrochemical Properties
Abstract
The synthesis and structural characterization of a new liquid crystalline coordination complex based on pentacoordinated Zn(II) metal centre with the coordination fulfilled by the tridentate chelating N^N^N 2,2′;6′,2″-terpyridine ligand and two monoanionic gallates decorated with several long alkyl chains is described. The mesomorphic properties were accurately investigated by small- and wide-angle X-ray scattering studies. Despite the bulky coordination around the metal centre, the complex self-organizes into a smectic phase and, based on the structural and geometrical parameters, a model for the supramolecular organization in the liquid crystalline phase is proposed. Electrochemical investigations showed the importance of the molecular structure of the coordination complex in enhancing its aqueous sensing capacities: the bulky organic ligands form an organic shell separating the metal centres and favouring the redox system through their reduction followed by stripping.