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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Karlsson, Stefan
RISE Research Institutes of Sweden
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Corrigendum to “Viscosity of alumina doped soda lime silicate glasses – observation of anomaly in the linear increase as Al2O3 replaces SiO2” [Journal of Non-Crystalline Solids Vol 573 (2021) start 121149]
- 2023Transparent multifunctional cover glass coating for solar energy applications
- 2023Durability of antireflective SiO2 coatings with closed pore structurecitations
- 2023Effects of deposition temperature on the mechanical and structural properties of amorphous Al–Si–O thin films prepared by radio frequency magnetron sputteringcitations
- 2023Effects of deposition temperature on the mechanical and structural properties of amorphous Al-Si-O thin films prepared by radio frequency magnetron sputteringcitations
- 2022Mechanical, thermal, and structural investigations of chemically strengthened Na2O–CaO–Al2O3–SiO2 glassescitations
- 2022Dataset: Alkali Ion diffusion and structure of chemically strengthened TiO2 doped soda-lime silicate glass ; Dataset: Alkali jon diffusion och struktur för kemiskt härdade TiO2 dopade soda kalk silikatglas
- 2022Non-destructive testing of the glass strength in flat glass with indentationinduced cracks by Nonlinear Acoustic Wave method
- 2022Compositional Effects on Indentation Mechanical Properties of Chemically Strengthened TiO2-Doped Soda Lime Silicate Glassescitations
- 2022Alkali ion diffusion and structure of chemically strengthened TiO2 doped soda-lime silicate glasscitations
- 2022Dataset: Mechanical, thermal, and structural investigations of chemically strengthened Na2O–CaO–Al2O3–SiO2 glasses ; Dataset: Mekaniska, termiska och strukturella undersökningar av kemiskt härdade Na2O–CaO–Al2O3–SiO2 glas
- 2021Viscosity of alumina doped soda lime silicate glasses – observation of anomaly in the linear increase as Al2O3 replaces SiO2citations
- 2021Strength classification of flat glass for better quality – validation of method by well-defined surface defects and strength testing ; Hållfasthetsklassificering av planglas för bättre kvalitet – validering av metod genom kontrollerade ytdefekter och hållfasthetsprovning
- 2019Simultaneous chemical vapor deposition and thermal strengthening of glasscitations
- 2019Mixed alkali/alkaline earth-silicate glasses : Physical properties and structure by vibrational spectroscopycitations
- 2016Effect of TiO2 on optical properties of glasses in the soda-lime-silicate systemcitations
- 2015Quantitative image analysis for evaluating the abrasion resistance of nanoporous silica films on glasscitations
- 2015Alkali salt vapour deposition and in-line ion exchange on flat glass surfacescitations
- 2014Chemical strengthening of flat glass by vapour deposition and in-line alkali metal ion exchange
- 2012Modification of Float Glass Surfaces by Ion Exchange
Places of action
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article
Mechanical, thermal, and structural investigations of chemically strengthened Na2O–CaO–Al2O3–SiO2 glasses
Abstract
For a series of conventional soda-lime-silicate glasses with increasing Al2O3 content, we investigated the thermal, mechanical, and structural properties before and after K+-for-Na+ ion-exchange strengthening by exposure to molten KNO3. The Al-for-Si replacement resulted in increased glass network polymerization and lowered compactness. The glass transition temperature (Tg), hardness (H) and reduced elastic modulus (Er), of the pristine glasses enhanced monotonically for increasing Al2O3 content. H and Er increased linearly up to a glass composition with roughly equal stoichiometric amounts of Na2O and Al2O3 where a nonlinear dependence on Al2O3 was observed, whereas H and Er of the chemically strengthened (CS) glasses revealed a strictly linear dependence. Tg, on the other hand, showed linear increase with Al-for-Si for pristine glasses while for the CS glasses a linear to nonlinear trend was observed. Solid-state 27Al nuclear magnetic resonance (NMR) revealed the sole presence of AlO4 groups in both the pristine and CS glasses. 23Na NMR and wet-chemical analysis manifested that all Al-bearing glasses had a lower and near-constant K+-for-Na+ ion exchange ratio than the soda-lime-silicate glass. Differential thermal analysis of CS glasses revealed a “blurred” glass transition temperature (Tg) and an exothermic step below Tg; the latter stems from the relaxation of residual compressive stresses. The nanoindentation-derived hardness at low loads and <5 mol% Al2O3 showed evidence of stress relaxation for prolonged ion exchange treatment. The crack resistance is maximized for molar ratios n(M(2)O)/n(Al2O3)≈1≈1 for the CS glasses, which is attributed to an increased elastic energy recovery that is linked to the glass compactness. ; Funding: Forsknignsrådet Formas 2018-00707 ; Tunnare och starkare glas för hållbar produktion och konsumtion