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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Deville, Sylvain
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (28/28 displayed)
- 2022Nacre-like alumina composites reinforced by zirconia particlescitations
- 2022Toughening mechanisms in nacre-like alumina revealed by in-situ imaging of stresscitations
- 2021Mechanical properties of unidirectional, porous polymer/ceramic composites for biomedical applicationscitations
- 2020Nacre-like alumina composites based on heteroaggregationcitations
- 2020A simple approach to bulk bioinspired tough ceramicscitations
- 2020Determination of interface fracture properties by micro-and macro-scale experiments in nacre-like aluminacitations
- 2020Interface failure in nacre-like aluminacitations
- 2020Strength and toughness trade-off optimization of nacre-like ceramic compositescitations
- 2019Ice-templated poly(vinylidene fluoride) ferroelectretscitations
- 2019Elasticity and fracture of brick and mortar materials using discrete element simulationscitations
- 2018Synthesis of Functional Ceramic Supports by Ice Templating and Atomic Layer Depositioncitations
- 2018Five-dimensional imaging of freezing emulsions with solute effectscitations
- 2018Synthesis of functional ceramic supports by ice templating and atomic layer depositioncitations
- 2018Reply to the correspondence:" On the fracture toughness of bioinspired ceramic materials"
- 2018Ice-templated poly(vinylidene fluoride) ferroelectretscitations
- 2017Fabrication of ice-templated tubes by rotational freezing: Microstructure, strength, and permeabilitycitations
- 2014Strong, tough and stiff bioinspired ceramics from brittle constituentscitations
- 2014Lightweight and stiff cellular ceramic structures by ice templatingcitations
- 2014Strong, tough and stiff bioinspired ceramics from brittle constituentscitations
- 2014Templated Grain Growth in Macroporous Materialscitations
- 2011Reliability assessment in advanced nanocomposite materials for orthopaedic applicationscitations
- 2011Dynamics of the Freezing Front During the Solidification of a Colloidal Alumina Aqueous Suspension: In Situ X-Ray Radiography, Tomography, and Modelingcitations
- 2009Metastable and unstable cellular solidification of colloidal suspensionscitations
- 2007Fabrication andin vitro characterization of three-dimensional organic/inorganic scaffolds by robocastingcitations
- 2004Martensitic transformation in zirconia, part II : martensitic growth
- 2004Accelerated aging in 3mol.p.c. yttria stabilized zirconia ceramics sintered in reducing conditions
- 2004Modeling the aging kinetics of zirconia ceramics
- 2003Low-temperature ageing of zirconia-toughened alumina ceramics and its implication in biomedical implants
Places of action
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article
Synthesis of functional ceramic supports by ice templating and atomic layer deposition
Abstract
<p>In this work, we report an innovative route for the manufacturing of functional ceramic supports, by combining ice templating of yttria stabilized zirconia (YSZ) and atomic layer deposition (ALD) of Al<sub>2</sub>O<sub>3</sub>processes. Ceramic YSZ monoliths are prepared using the ice-templating process, which is based on the controlled crystallization of water following a thermal gradient. Sublimation of the ice and the sintering of the material reveal the straight micrometer sized pores shaped by the ice crystal growth. The high temperature sintering allows for the ceramic materials to present excellent mechanical strength and porosities of 67%. Next, the conformality benefit of ALD is used to deposit an alumina coating at the surface of the YSZ pores, in order to obtain a functional material. The Al<sub>2</sub>O<sub>3</sub>thin films obtained by ALD are 100 nm thick and conformally deposited within the macroporous ceramic supports, as shown by SEM and EDS analysis. Mercury intrusion experiments revealed a reduction of the entrance pore diameter, in line with the growth per cycle of 2 Å of the ALD process. In addition to the manufacture of the innovative ceramic nanomaterials, this article also describes the fine characterization of the coatings obtained using mercury intrusion, SEM and XRD analysis.</p>