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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Österberg, Monika
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Topics
Publications (26/26 displayed)
- 2024Biodegradation of Lignocellulose-Polyester Composite Films in Freshwater and Seawater Conditionscitations
- 2024Adsorption of sulphonated lignin-carbohydrate complexes (LCCs) onto cellulose surfaces
- 2024Hydrophobized lignin nanoparticle-stabilized Pickering foams : building blocks for sustainable lightweight porous materialscitations
- 2023Characterization of cell-biomaterial adhesion forces that influence 3D cell culture
- 2022Durable Biopolymer Films From Lignin-Carbohydrate Complex Derived From a Pulp Mill Side Streamcitations
- 2022Hybrid films from cellulose nanomaterials—properties and defined optical patternscitations
- 2021Durable Biopolymer Films From Lignin-Carbohydrate Complex Derived From a Pulp Mill Side Streamcitations
- 2021Cellulose nanofibers/lignin particles/tragacanth gum nanocomposite hydrogels for biomedical applications
- 2021Colloidal Lignin Particles and Epoxies for Bio-Based, Durable, and Multiresistant Nanostructured Coatingscitations
- 2021Tuning the functional properties of lignocellulosic films by controlling the molecular and supramolecular structure of lignincitations
- 2021Toward waste valorization by converting bioethanol production residues into nanoparticles and nanocomposite filmscitations
- 2020Three-Dimensional Printed Cell Culture Model Based on Spherical Colloidal Lignin Particles and Cellulose Nanofibril-Alginate Hydrogelcitations
- 2020Three-Dimensional Printed Cell Culture Model Based on Spherical Colloidal Lignin Particles and Cellulose Nanofibril-Alginate Hydrogelcitations
- 2020Observing microfibril bundles in wood by small-angle neutron scattering
- 2020Bundling of cellulose microfibrils in native and polyethylene glycol-containing wood cell walls revealed by small-angle neutron scatteringcitations
- 2020Moisture-related changes in the nanostructure of woods studied with X-ray and neutron scatteringcitations
- 2019Understanding hemicellulose-cellulose interactions in cellulose nanofibril-based compositescitations
- 2019Small-angle scattering model for efficient characterization of wood nanostructure and moisture behaviourcitations
- 2019Strong, Ductile, and Waterproof Cellulose Nanofibril Composite Films with Colloidal Lignin Particlescitations
- 2017Layer-by-layer assembled hydrophobic coatings for cellulose nanofibril films and textiles, made of polylysine and natural wax particles
- 2017Adsorption of Proteins on Colloidal Lignin Particles for Advanced Biomaterialscitations
- 2016Electrochemical detection of hydrogen peroxide on platinum-containing tetrahedral amorphous carbon sensors and evaluation of their biofouling propertiescitations
- 2015Correlation between cellulose thin film supramolecular structures and interactions with watercitations
- 2015Electrochemical detection of hydrogen peroxide on platinum-containing tetrahedral amorphous carbon sensors and evaluation of their biofouling propertiescitations
- 2013Non-ionic assembly of nanofibrillated cellulose and polyethylene glycol grafted carboxymethyl cellulose and the effect of aqueous lubrication in nanocomposite formationcitations
- 2012Interactions between inorganic nanoparticles and cellulose nanofibrilscitations
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article
Durable Biopolymer Films From Lignin-Carbohydrate Complex Derived From a Pulp Mill Side Stream
Abstract
Funding Information: This document is part of a project that has received funding from the Bio Based Industries Joint Undertaking (JU) under the European Union?s Horizon 2020 research and innovation programme under grant agreement No. 837866. The JU receives support from the European Union?s Horizon 2020 research and innovation programme and the Bio Based Industries Consortium. Publisher Copyright: Copyright © 2021 Asikanius, Jääskeläinen, Koivula, Oinonen and Österberg. ; Valorization of side streams offers novel types of raw materials to complement or replace synthetic and food-based alternatives in materials science, increasing profitability and decreasing the environmental impacts of biorefineries. Lignocellulose biomass contains lignin and carbohydrates that are covalently linked into lignin-carbohydrate complexes (LCCs). In biomass fractionation processes, these complexes are conventionally considered as waste, which hinders the biomass fractionation process, and they may solubilize into aqueous effluents. This study presents how LCCs, derived from pulp mill effluent, can be turned into valuable biopolymers for industrial polymer film applications. Free-standing composite films containing hydroxyethyl cellulose (HEC) and LCCs with varying molar mass, charge density and lignin/hemicellulose ratio were prepared to study the effect of LCC amount on mechanical properties and oxygen permeability. Increasing the LCC content increased the yield point and Young’s modulus of the films. Breaking strain measurements revealed a non-linear correlation with the LCC concentration for the samples with higher lignin than hemicellulose content. The addition of LCC enhanced oxygen barrier properties of HEC films significantly even at high relative humidity. The present research demonstrates how a currently underutilized fraction of the biorefinery side stream has the potential to be valorized as a biopolymer in industrial applications, for example as a barrier film for paper and board packaging. ; Peer reviewed