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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Šljukić, Biljana
University of Lisbon
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023From PET Bottles Waste to N-Doped Graphene as Sustainable Electrocatalyst Support for Direct Liquid Fuel Cellscitations
- 2023Combining silver, polyaniline and polyvinylpyrrolidone for efficient electrocatalysis of borohydride oxidation reactioncitations
- 2023Effect of carbon support on the activity of monodisperse Co45Pt55 nanoparticles for oxygen evolution in alkaline mediacitations
- 2023In-situ grafting of Fe and Cu nanoparticles on carbon for electrolytic hydrogen production
- 2022Facile Synthesis of Low-Cost Copper-Silver and Cobalt-Silver Alloy Nanoparticles on Reduced Graphene Oxide as Efficient Electrocatalysts for Oxygen Reduction Reaction in Alkaline Mediacitations
- 2022High-performance metal (Au,Cu)–polypyrrole nanocomposites for electrochemical borohydride oxidation in fuel cell applicationscitations
- 2022Electrocatalytic Behavior of an Amide Functionalized Mn(II) Coordination Polymer on ORR, OER and HERcitations
- 2022Platinum–Dysprosium Alloys as Oxygen Electrodes in Alkaline Media: An Experimental and Theoretical Studycitations
- 2021Tailoring gold-conducting polymer nanocomposites for sensors applications: Proof of concept for As(III) sensing in aqueous mediacitations
- 2021Ionic Liquid-Derived Carbon-Supported Metal Electrocatalysts as Anodes in Direct Borohydride-Peroxide Fuel Cellscitations
- 2020Bimetallic Co-Based (CoM, M = Mo, Fe, Mn) Coatings for High-Efficiency Water Splittingcitations
- 2019Gold nanorod-polyaniline composites: Synthesis and evaluation as anode electrocatalysts for direct borohydride fuel cellscitations
Places of action
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article
Effect of carbon support on the activity of monodisperse Co45Pt55 nanoparticles for oxygen evolution in alkaline media
Abstract
<jats:p>Oxygen evolution reaction (OER) represents the efficiency-limiting reaction in water electrolyzers, metal-air batteries, and unitized regenerative fuel cells. To achieve high-efficiency OER in alkaline media, we fabricated three novel electrocatalysts by the assembly of as-prepared Co<jats:sub>45</jats:sub>Pt<jats:sub>55</jats:sub> alloy nanoparticles (NPs) on three different carbon-based support materials: reduced graphene oxide (CoPt/rGO), mesoporous graphitic carbon nitride (CoPt/mpg-CN), and commercial Ketjenblack carbon (CoPt/KB). Voltammetry studies revealed that CoPt/rGO electrocatalyst provided lower OER overpotentials accompanied by higher currents and specific current density values than the other two studied materials. Moreover, CoPt/rGO outperformed commercial CoPt/C electrocatalysts in terms of notably higher specific current densities. Additionally, it was found that CoPt/rGO electrocatalyst activity increases with increasing temperature up to 85°C, as suggested by the increase in the exchange current density. Electrochemical impedance spectroscopy studies of three electrocatalysts in OER revealed similar charge transfer resistance, although CoPt/rGO provided a higher current density. The main issue observed during long-term chronoamperometry and chronopotentiometry studies is the materials’ instability under OER polarization conditions, which is still to be tackled in future work.</jats:p>