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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Parkinson, Patrick
University of Manchester
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (11/11 displayed)
- 2023Heterometallic lanthanide complexes with site-specific binding that enable simultaneous visible and NIR-emissioncitations
- 2021Measuring, controlling and exploiting heterogeneity in optoelectronic nanowirescitations
- 2020Spatially and temporally resolved degradation in antisolvent treated perovskite films
- 2020Spatially and temporally resolved degradation in antisolvent treated perovskite films
- 2019Effect of size on the luminescent efficiency of perovskite nanocrystalscitations
- 2016Characterization of a silica-PVA hybrid for high density and stable silver dissolutioncitations
- 2013III-V semiconductor nanowires for optoelectronic device applicationscitations
- 2012Polarization tunable, multicolor emission from core-shell photonic III-V semiconductor nanowirescitations
- 2011III-V semiconductor nanowires for optoelectronic device applicationscitations
- 2008Efficient generation of charges via below-gap photoexcitation of polymer-fullerene blend films investigated by terahertz spectroscopycitations
- 2007Dimensionality-dependent energy transfer in polymer-intercalated SnS2 nanocompositescitations
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article
Heterometallic lanthanide complexes with site-specific binding that enable simultaneous visible and NIR-emission
Abstract
Macrocyclic lanthanide complexes have become widely developed due to their distinctive luminescence characteristics and wide range of applications in biological imaging. However, systems with sufficient brightness and metal selectivity can be difficult to produce on a molecular scale. Presented herein is the stepwise introduction of differing lanthanide ions in a bis-DO3A/DTPA scaffold to afford three trinuclear bimetallic [Ln 2 Ln’] lanthanide complexes with site-specific, controlled binding [(Yb 2 Tb), (Eu 2 Tb), (Yb 2 Eu)]. The complexes display simultaneous emission from all Ln III centers across the visible (Tb III , Eu III ) and near infra-red (Yb III ) spectrum when excited via phenyl ligand sensitization at a wide range of temperatures and are consequently of interest for exploiting imaging in the near infra-red II biological window. Analysis of lifetime data over a range of excitation regimes reveals intermetallic communication between Tb III and Eu III centers and further develops the understanding of multimetallic lanthanide complexes.