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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Giurlani, Walter
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Electrodeposition of Sn-Ru Alloys by Using Direct, Pulsed, and Pulsed Reverse Current for Decorative Applicationscitations
- 2024On the Electrochemical Growth of a Crystalline p–n Junction From Aqueous Solutionscitations
- 2024Electrodeposition of Nanostructured Metals on n-Silicon and Insights into Rhodium Deposition
- 2024Pulse Electroplating of Gold-Nickel Alloys: Morphological and Aesthetic Improvement Compared to DCcitations
- 2023Spin-dependent charge transmission through chiral 2T3N self-assembled monolayer on Aucitations
- 2023Spin-dependent charge transmission through chiral 2T3N self-assembled monolayer on Aucitations
- 2023Chiral “doped” MOFs: an electrochemical and theoretical integrated studycitations
- 2022Magnetic Field Effect on the Handedness of Electrodeposited Heusler Alloycitations
- 2022Electroplating on Al6082 Aluminium: A New Green and Sustainable Approachcitations
- 2022A systematic study of pulse and pulse reverse plating on acid copper bath for decorative and functional applicationscitations
- 2021Electrodeposition of Cu on PEDOT for a Hybrid Solid-State Electronic Devicecitations
- 2019Electrodeposition and innovative characterization of precious metal alloys for the Galvanic and Jewel industry
- 2018Electroplating for Decorative Applications: Recent Trends in Research and Developmentcitations
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article
Chiral “doped” MOFs: an electrochemical and theoretical integrated study
Abstract
<jats:p>This work reports on the electrochemical behaviour of Fe and Zn based metal-organic framework (MOF) compounds, which are “doped” with chiral molecules, namely: cysteine and camphor sulfonic acid. Their electrochemical behaviour was thoroughly investigated via “solid-state” electrochemical measurements, exploiting an “<jats:italic>ad hoc</jats:italic>” tailored experimental set-up: a paste obtained by carefully mixing the MOF with graphite powder is deposited on a glassy carbon (GC) surface. The latter serves as the working electrode (WE) in cyclic voltammetry (CV) measurements. Infrared (IR), X-ray diffraction (XRD) and absorbance (UV-Vis) techniques are exploited for a further characterization of the MOFs’ structural and electronic properties. The experimental results are then compared with DFT based quantum mechanical calculations. The electronic and structural properties of the MOFs synthesized in this study depend mainly on the type of metal center, and to a minor extent on the chemical nature of the dopant.</jats:p>