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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Domenech, Trystan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Competition between bead boundary fusion and crystallization kinetics in material extrusion-based additive manufacturingcitations
- 2016Three distinct open-pore morphologies from a single particle-filled polymer blendcitations
- 2014Formation of Fractal-like Structure in Organoclay-Based Polypropylene Nanocompositescitations
- 2013The importance of specific mechanical energy during twin screw extrusion of organoclay based polypropylene nanocompositescitations
- 2012Influence of twin-screw processing conditions on structure and properties of polypropylene - Organoclay nanocompositescitations
- 2012Influence of Twin-Screw Processing Conditions on Structure and Properties of Polypropylene – Organoclay Nanocompositescitations
- 2012Time-evolution of the structure of organoclay/polypropylene nanocomposites and application of the time/temperature superposition principlecitations
- 2012Shear-induced structure evolution in organoclay/polypropylene nanocomposites: transient behaviour and relaxation.
- 2011Influence of twin-screw extrusion processing conditions on the structure of nanocomposites and characterization by rheometry
- 2011Time-evolution of the structure of organoclay/ polypropylene nanocomposites and its influence on time/temperature superposition principle
- 2011Nanocomposites à matrice polypropylène : caractérisation de l'état de dispersion et suivi de l'évolution microstructurale par rhéologie
- 2011Influence of twin-screw processing conditions on structure and properties of polypropylene - organoclay nanocomposites
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article
Influence of Twin-Screw Processing Conditions on Structure and Properties of Polypropylene – Organoclay Nanocomposites
Abstract
<jats:title>Abstract</jats:title><jats:p>This study looks at the influence of extrusion parameters such as screw speed, feed rate and barrel temperature on the nanocomposite structure (size of agglomerates, level of intercalation and exfoliation) and its consequences on final mechanical properties. Nanocomposites of polypropylene, maleated polypropylene and organomodified montmorillonite, with respective mass fractions of 85/10/5, were prepared in a co-rotating twin-screw extruder using a masterbatch dilution method. The nanocomposites structure was quantified by scanning and transmission electron microscopy, X-ray diffraction and dynamic rheometry. Relationships between the microstructure at different levels (size and number of agglomerates, interlayer distance, melt yield stress to quantify the exfoliation level) and the processing conditions were established, revealing that specific mechanical energy received during extrusion was the key parameter controlling this microstructure. Mechanical properties in uniaxial tension (apparent Young's modulus) were measured and related to the microstructural parameters resulting from extrusion conditions.</jats:p>