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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Jacob, Timo
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Process optimization of the morphological properties of epoxy resin molding compounds using response surface designcitations
- 2024Insights into electrode–electrolyte interfaces by in situ scanning tunnelling microscopy
- 2024Conjugated Polyimidazole Nanoparticles as Biodegradable Electrode Materials for Organic Batteries
- 2024In situ monitoring of the curing of highly filled epoxy molding compounds: the influence of reaction type and silica content on cure kinetic modelscitations
- 2024Optimizing epoxy molding compound processing: a multi-sensor approach to enhance material characterization and process reliability
- 2023Entropic contributions to sodium solvation and solvent stabilization upon electrochemical sodium deposition from diglyme and propylene carbonate electrolytes
- 2023Fully-conjugated polyimidazole nanoparticles as active material in biodegradable electrodes for organic batteries
- 2023Conjugated polyimidazole nanoparticles as biodegradable electrode materials for organic batteriescitations
- 2022First‐Principles Studies on the Atomistic Properties of Metallic Magnesium as Anode Material in Magnesium‐Ion Batteries
- 2022First-principles studies on the atomistic properties of metallic magnesium as snode material in magnesium-ion batteries
- 2022Initial Stages of Sodium Deposition onto Au(111) from [MPPip][TFSI]: An In‐Situ STM Study for Sodium‐Ion Battery Electrolytes
- 2022An interfacial study of Au(111) electrodes in deep eutectic solvents
- 2021Electrodeposition of Zinc onto Au(111) and Au(100) from the Ionic Liquid [MPPip][TFSI]
- 2021Hydrogen Peroxide Oxidation Reaction on a 4-Mercaptopyridine Self-Assembled Monolayer on Au(111) Metallized by Platinum Nanoislandscitations
- 2019Synthesis, structural and morphological characterizations of nano-Ru-based perovskites/RGO composites
- 2019Synthesis, structural and morphological characterizations of nano-Ru-based perovskites/RGO compositescitations
- 2019An electrochemical route for hot alkaline blackening of steel: a nitrite free approach.
- 2019Towards quantitative treatment of electron pair distribution functioncitations
- 2018Electrocatalytic Behavior of Pd and Pt Nanoislands Deposited onto 4,4′-Dithiodipyridine SAMs on Au(111)citations
- 2017Stabilization of Low-Valent Iron(I) in a High-Valent Vanadium(V) Oxide Clustercitations
- 2012Surface Modification of a n-Si(111) Electrode through Aldehyde Grafting and Subsequent Metallization: Theory and Experiment
- 2011Au@Hg Nanoalloy Formation Through Direct Amalgamation: Structural, Spectroscopic, and Computational Evidence for Slow Nanoscale Diffusioncitations
Places of action
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document
Fully-conjugated polyimidazole nanoparticles as active material in biodegradable electrodes for organic batteries
Abstract
<jats:p>Conjugated polymers are promising active materials for batteries. Batteries not only need to have high energy density but should also combine safe handling with recyclability or biodegradability after reaching their end-of-life. Here, we develop π-conjugated polyimidazole particles, which we prepare using atom economic direct arylation adapted to a dis-persion polymerization protocol. The synthesis yields polyimidazole nanoparticles with tunable size and narrow dispersi-ty. In addition, the degree of crosslinking of the polymer particles can be controlled. We demonstrate that the polyimid-azole nanoparticles can be processed together with carbon black and biodegradable carboxymethyl cellulose binder as active material for organic battery electrodes. Electrochemical characterization shows that a higher degree of crosslink-ing significantly improves the electrochemical processes and leads to clearer oxidation and reduction signals from the polymer. Polyimidazole as part of the composite electrode shows complete degradation by exposure to composting bac-teria over the course of 72 h.</jats:p>