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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Schneider, Christian
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2023Effect of Particle Size and Pressure on the Transport Properties of the Fast Ion Conductor t-Li7SiPS8citations
- 2022Effect of Particle Size and Pressure on the Transport Properties of the Fast Ion Conductor t-Li7SiPS8
- 2021Ultrathin Ga2O3 Glasscitations
- 2020Correction: Micro-spectroscopy of HKUST-1 metal–organic framework crystals loaded with tetracyanoquinodimethane: effects of water on host–guest chemistry and electrical conductivity
- 2020Strain-tunable single photon sources in WSe2 monolayerscitations
- 2019Micro-spectroscopy of HKUST-1 metal-organic framework crystals loaded with tetracyanoquinodimethane: effects of water on host-guest chemistry and electrical conductivitycitations
- 2019Micro-spectroscopy of HKUST-1 metal-organic framework crystals loaded with tetracyanoquinodimethane: effects of water on host-guest chemistry and electrical conductivity
- 2019Integration of atomically thin layers of transition metal dichalcogenides into high-Q, monolithic Bragg-cavities:an experimental platform for the enhancement of optical interaction in 2D-materialscitations
- 2019Integration of atomically thin layers of transition metal dichalcogenides into high-Q, monolithic Bragg-cavities : an experimental platform for the enhancement of optical interaction in 2D-materialscitations
- 2019Optimization of the specimen geometry of unidirectional reinforced composites with a fibre orientation of 90° for tensile, quasi-static and fatigue tests
- 2019Strain-tunable single photon sources in WSe 2 monolayerscitations
- 2019Towards polariton blockade of confined exciton–polaritonscitations
- 2019Towards polariton blockade of confined exciton–polaritonscitations
- 2018High electrical conductivity and high porosity in a Guest@MOF material : Evidence of TCNQ ordering within Cu3BTC2 microporescitations
- 2016Electrical Conductivity and Morphology Changes of HKUST-1 single crystals and thin films upon exposure to TCNQ.
- 2013Energy-resolved magnetic domain imaging in TbCo alloys by valence band photoemission magnetic circular dichroismcitations
- 2013Spatiotemporal characterization of SPP pulse propagation in two-dimensional plasmonic focusing devicescitations
- 2011Electrically Driven Quantum Dot Micropillar Light Sourcescitations
- 2004Modellierung des Dehnvorgangs von Polymerschmelzen bei der Drahtummantelung im Schlauchreckverfahren mit Hilfe uniaxialer Dehnexperimente
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article
Effect of Particle Size and Pressure on the Transport Properties of the Fast Ion Conductor t-Li7SiPS8
Abstract
<jats:p>All-solid-state batteries promise higher energy and power densities as well as increased safety compared to lithium ion batteries, by using non-flammable solid electrolytes and metallic lithium as the anode. As the liquid electrolyte is replaced by a solid electrolyte, ensuring permanent and close contact between the various components as well as between the individual particles is key for the long-term operation of a solid-state cell. Currently, there are few studies on how a solid-state electrolyte behaves when compressed by external pressure. Here we present a study in which the compression mechanics and ionic conductivity evolution of the fast solid-state conductor Li7SiPS8 were investigated under pressure on two samples with different particle sizes. In operando electrochemical impedance spectroscopy under pressure allows the determination of the activation volume of Li7SiPS8. In addition to the experiments under pressure, we show that the determined ionic conductivity additionally depends on the contact pressure. Furthermore, we simulate pelletizing using the discrete element method followed by finite volume analysis, where the effect of the pressure dependent microstructure can be distinguished from the atomistic effect of the activation volume. We conclude not only that the pelletizing pressure is an important parameter for describing the ionic conductivity of a solid, but also the particle size and morphology as well as the contact pressure during the measurement affect the impedance of a solid tablet. Furthermore, the relative density of a tablet is a weaker descriptor for the sample's impedance, compared to the particle size distribution.</jats:p>