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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Almeida, Olivier De
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2022Determination of a degradation-induced limit for the consolidation of CF/PEEK composites using a thermo-kinetic viscosity modelcitations
- 2021Effect of PEEK degradation on commingled fabrics consolidation
- 2021Effect of melt spinning on the integrity of poly(ether ether ketone) for commingled yarn based composite preformscitations
- 2021Effect of poly(ether ether ketone) degradation on commingled fabrics consolidationcitations
- 2020Characterisation and modelling of the temperature and rate dependent shear behaviour of a non-consolidated powder impregnated fabric
- 2019Experimental characterization and modeling of the temperature and rate-dependent shear behaviour of powder-impregnated glass fiber/PA66 woven semipregscitations
- 2019Modelling strategy of IR lamps with integrated reflector used in the manufacturing processof thermoplastic composite tapes
- 2019Pixel Coloring modelling of PEKK crystallization
- 2019Modeling of IR lamps with coated reflector used in the slurry powder impregnation process of composite tapescitations
- 2018The role of microcrystalline structure on optical scattering characteristics of semi-crystalline thermoplastics and the accuracy of numerical input for IR-heating modelingcitations
- 2017Experimental study of polymerization and crystallization kinetics of polyamide 6 obtained by anionic ring opening polymerization of ε-caprolactamcitations
- 2017Towards a coupled heating-forming simulation of the thermoforming of thermoplastic compositescitations
- 2017Long term ageing of polyamide 6 and polyamide 6 reinforced with 30% of glass fibers: physicochemical, mechanical and morphological characterizationcitations
- 2017A non-invasive experimental approach for surface temperature measurements on semi-crystalline thermoplasticscitations
- 2016Assessment of induction heated mould technologies for high-temperature thermoplastic composite manufacturing
- 2016Experimental analysis on the coupled effect between thermo-optical properties and microstructure of semi-crystalline thermoplasticscitations
- 2016Coupled heating-forming simulation of the thermoforming of thermoplastic composites
- 2016Identification of the temperature dependent relation between thermo-optical properties and morphology of semi-crystalline thermoplastics for thermoforming process
- 2010Melt state behaviour of PEEK and processing window interpretation for fast compression moulding process
- 2010Heterogeneous tensile behavior of impact-modified polypropylene plates processed by injection moulding
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document
Effect of PEEK degradation on commingled fabrics consolidation
Abstract
The effects of PEEK degradation on consolidation of commingled semi-finished products have been investigated. Two commingled semi-finished products provided by two different suppliers have been studied and compared to a powdered fabric based on the same PEEK grade. Both were manufactured from aligned AS4 carbon and PEEK yarns but the first product referred as the NCF1 has a lower commingling level than the second one identified as the NCF2. Contrary to what could be expected, under the same processing conditions, consolidation of the NCF1 and the NCF2 systematically results in a high porosity content, above 10%. Fourier Transform Infrared spectrophotometry (FTIR) in ATR mode and Gel Permeation Chromatography (GPC) have shown small molecular structure modifications of PEEK yarns compared to the raw material, such as a shift of molar mass distributions towards lower molar mass and the appearance of C-H absorption bands attributed to non-aromatic alkanes. These modifications have been attributed to sizing of PEEK filament. Calorimetric (DSC) and rheological analyses have demonstrated that the presence of sizing in the semifinished products have huge consequences on the degradation kinetics. The crystallization temperature decreases and the viscosity increases significantly. This acceleration of the degradation kinetics is the reason of the poor consolidation behavior during composite manufacturing. The conditions of melt spinning extrusion under which the neat PEEK is transformed into filament are therefore a key factor of PEEK degradation.