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Zivkovic, Sanja
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article
Synthesis and spectroscopic characterization of new solid solution containing Mg(II) and Cu(II) complexes with hexadentate 1,3-propanediaminen, N,N’,N’-tetraacetate (1,3-pdta) ligand: In vitro antifungal activity of 1,3-pdta-Cu(II) complexes
Abstract
<jats:p>New solid solution containing Mg(II) and Cu(II) complexes with hexadentate1,3-propanediamine-N,N,N?,N?-tetraacetate ligand (1,3-pdta), [Mg(H2O)6][Mg0.5Cu0.5(1,3-pdta)].2H2O was synthesized and structurally characterizedby elemental microanalyses, molar conductivity, and spectroscopic (IR andUV-Vis) measurements. The spectroscopic data of[Mg(H2O)6][Mg0.5Cu0.5(1,3-pdta)].2H2O were compared with those for[Mg(H2O)6][Cu(1,3-pdta)].2H2O complex of the known molecular structuredetermined by single-crystal X-ray diffraction analysis. In vitro growthinhibition activity of [Mg(H2O)6][Mg0.5Cu0.5(1,3-pdta)].2H2O and[Mg(H2O)6][Cu(1,3-pdta)].2H2O against Colletotrichum acutatum and theireffects on this fungus sporulation level are investigated. The obtainedresults showed that the highest percentage of inhibition for mycelium growthwas achieved at a concentration of 500 ?g/mL for the investigated complexes.The biological activities of the investigated complexes were compared withthose for the commercial formulation of fungicide captan (Method 480 SC).</jats:p>