• Skogby, Henrik
• Lepore, Giovanni Orazio
• Taddei, Alice
• Bonazzi, Paola
• Bindi, Luca

Abstract

<jats:title>Abstract</jats:title><jats:p>Hydropyrochlore, ideally (H2O,)2Nb2(O,OH)6(H2O), is a cubic mineral (space group Fd3m, a = 10.56-10.59 Å, Z = 8) belonging to the pyrochlore supergroup (general formula: A2−mB2X6−wY1−n). The K-rich variety of this species is unique to the Lueshe syenitic-carbonatitic deposit (D.R. Congo), where it occurs as the alteration product of primary (Ca,Na)2Nb2O6F pyrochlores. The structure of this mineral is made of a B2X6 (B = Nb, Ti; X = O, OH) framework that generates tunnels along the [110] direction, where the interstitial sites are partially occupied by water molecules and minor amounts of different cations. These features form the basis for the ion-exchange properties of hydropyrochlore, making it a promising candidate as a mineral sink for heavy metals (e.g., Tl+) dispersed in aqueous matrices, with interesting environmental implications.</jats:p><jats:p>Tl+ incorporation was induced through imbibition experiments in a diluted Clerici solution using single crystals of hydropyrochlore from Lueshe (D.R. Congo); the modifications induced by Tl+ incorporation were then evaluated through single-crystal X-ray diffraction (SCXRD), electron microprobe analyses (EMPA) and Fourier transform infrared (FT-IR) spectroscopy.</jats:p><jats:p>After Tl+ imbibition, a dramatic increase of the A-site electron density (n.e− from ~4 to ~60) confirms the entry of a substantial amount of Tl+ at this site (up to about 70%), leading to a lengthening of the A-X distances and the consequent expansion of the unit cell. A decrease of the site scattering at the Y' site (from ~9 to ~4 e−) also occurs, suggesting a loss of aqueous species. Although the predominance of neutral H2O molecules at the interstitial sites of hydropyrochlore from Lueshe is widely accepted by the mineralogical community, our crystal-chemical and FT-IR data provide evidence that the dominant species might be the hydronium ion, with significant implications on the nomenclature of the pyrochlore supergroup.</jats:p><jats:p>Understanding the crystallographic aspects of hydropyrochlore as a potential waste form for monovalent thallium immobilization not only addresses a pressing environmental concern, but also contributes to the broader field of waste management.</jats:p>

Topics

• density
• impedance spectroscopy
• mineral
• single crystal
• x-ray diffraction
• experiment
• interstitial
• space group
• Thallium