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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Dyksik, Mateusz
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Bright Excitonic Fine Structure in Metal-Halide Perovskites: From Two-Dimensional to Bulkcitations
- 2024Exciton Fine Structure in 2D Perovskites: The Out-of-Plane Excitonic Statecitations
- 2024Polaronic Mass Enhancement and Polaronic Excitons in Metal Halide Perovskitescitations
- 2021Photophysics of Two-Dimensional Perovskites—Learning from Metal Halide Substitutioncitations
- 2021Photophysics of Two-Dimensional Perovskites—Learning from Metal Halide Substitution
- 2021Brightening of dark excitons in 2D perovskitescitations
- 2021Manganese doping for enhanced magnetic brightening and circular polarization control of dark excitons in paramagnetic layered hybrid metal-halide perovskitescitations
- 2021Manganese doping for enhanced magnetic brightening and circular polarization control of dark excitons in paramagnetic layered hybrid metal-halide perovskites.
- 2020Broad Tunability of Carrier Effective Masses in Two-Dimensional Halide Perovskitescitations
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article
Photophysics of Two-Dimensional Perovskites—Learning from Metal Halide Substitution
Abstract
Whereas their photophysics exhibits an intricate interplay of carriers with the lattice, most reports have so far relied on single compound studies. With the exception of variations of the organic spacer cations, the effect of constituent substitution on the photophysics and the nature of emitting species, in particular, has remained largely under-explored. Here PEA$_2$PbBr$_4$, PEA$_2$PbI$_4$, and PEA$_2$SnI$_4$ are studied through a variety of optical spectroscopy techniques to reveal a complex set of excitonic transitions at low temperature. We attribute the emergence of weak high energy features to a vibronic progression breaking Kasha's rule and highlight that the responsible phonons cannot be accessed through simple Raman spectroscopy. Bright peaks at lower energy are due to two distinct excitons, of which the upper is a convolution of a bright exciton and a localised state, whereas the lower is attributed to shallow defects. Our study offers deeper insights into the photophysics of two-dimensional perovskites through compositional substitution and highlights critical limits to the communities' current understanding of the photophysics of these compounds.