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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Clément, Sébastien
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2020Phosphonium‐based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self‐assembly and photovoltaic performancescitations
- 2020High-pressure, high temperature synthesis of a mesoporous α-quartz/bismuth nanowire compositecitations
- 2020Phosphonium-based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self-assembly and photovoltaic performances
- 2019Synthesis, characterization and modeling of self-assembled porphyrin nanorodscitations
- 2019High-pressure, high temperature insertion of bismuth in the siliceous zeolite silicalite-1citations
- 2017A self-assembly toolbox for thiophene-based conjugated polyelectrolytes: surfactants, solvent and copolymerisationcitations
- 2017A self-assembly toolbox for thiophene-based conjugated polyelectrolytes: surfactants, solvent and copolymerisation.
- 2016High-Permittivity Conjugated Polyelectrolyte Interlayers for High-Performance Bulk Heterojunction Organic Solar Cellscitations
- 2016Expanding the light absorption of poly(3-hexylthiophene) by end-functionalization with pi-extended porphyrinscitations
- 2014A facile synthesis of proton-conducting organic-inorganic membranescitations
- 2014Synthesis of TiO2-poly(3-hexylthiophene) Hybrid Particles through Surface-Initiated Kumada Catalyst-Transfer Polycondensationcitations
- 2012Synthesis and characterization of carboxystyryl end-functionalized poly(3-hexylthiophene) / TiO2 hybrids in view of photovoltaic applicationscitations
- 2010Synthesis and characterization of nanocomposites based on functional regioregular poly(3-hexylthiophene) and multiwall carbon nanotubescitations
- 2009In situ high pressure and high temperature Raman studies of (1-x)SiO2xGeO2 glassescitations
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article
Phosphonium-based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self-assembly and photovoltaic performances
Abstract
© 2020 Society of Industrial Chemistry Phosphonium-based polythiophene conjugated polyelectrolytes (CPEs) with three different counterions (dodecylsulfate, octylsulfate and perfluorooctane sulfonate) are synthesized to determine how the nature of the counterion affects the thermal properties, the self-assembly in thin films and the performance as the cathode interfacial layer in polymer solar cells (PSCs). The counterion has a significant effect on the thermal properties of the CPEs, affecting both their glass transition and crystalline behaviour. Grazing-incidence wide-angle X-ray scattering studies also indicate that changing the nature of the counterion influences the microstructural organization in thin films (face-on versus edge-on orientation). The affinity of the CPEs with the underlying photoactive layer in PSCs is highly correlated with the counterion species. Finally, in addition to an increase of the power conversion efficiency of ca 15% when using these CPEs as cathode interfacial layers in PSCs, a higher device stability is noted, compared to a reference device with a calcium interlayer. © 2020 Society of Industrial Chemistry.