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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Mehdi, Ahmad
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Easily deposited ZnO nanorods on siloxene nanosheets: investigation of morphological, dielectric, ferroelectric, and energy storage propertiescitations
- 2023Long-term stable solid concentrated graphene dispersion assisted by a highly aromatic ionic liquidcitations
- 2021Phosphonium-based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self-assembly and photovoltaic performancescitations
- 2020Phosphonium‐based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self‐assembly and photovoltaic performancescitations
- 2020Phosphonium-based polythiopheneconjugated polyelectrolytes with differentsurfactant counterions: thermal properties,self-assembly and photovoltaic performancescitations
- 2020Phosphonium-based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self-assembly and photovoltaic performances
- 2019Mesoporous Silica Colloids: Wetting, Surface Diffusion, and Cationic Surfactant Adsorptioncitations
- 2018Thulium-doped nanoparticles and their properties in silica-based optical fiberscitations
- 2017Vinylidene Fluoride-Based Polymer Network via Cross-Linking of Pendant Triethoxysilane Functionality for Potential Applications in Coatingscitations
- 2017Poly(vinylidene fluoride) Containing Phosphonic Acid as Anticorrosion Coating for Steelcitations
- 2016New organic-inorganic hybrid material based on a poly(amic acid) oligomer: a promising opportunity to obtain microfluidic devices by a photolithographic processcitations
- 2016Nanocomposites with both structural and porous hierarchy synthesized from Pickering emulsionscitations
- 2016Expanding the light absorption of poly(3-hexylthiophene) by end-functionalization with pi-extended porphyrinscitations
- 2014A facile synthesis of proton-conducting organic-inorganic membranescitations
- 2014Synthesis of TiO2-poly(3-hexylthiophene) Hybrid Particles through Surface-Initiated Kumada Catalyst-Transfer Polycondensationcitations
- 2014Single-ion conductor nanocomposite organic–inorganic hybrid membranes for lithium batteriescitations
- 2012Synthesis and characterization of carboxystyryl end-functionalized poly(3-hexylthiophene) / TiO2 hybrids in view of photovoltaic applicationscitations
- 2011EPR in functional structures based on doped (nano, meso)- porous silica and titanium dioxide
Places of action
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article
Phosphonium-based polythiophene conjugated polyelectrolytes with different surfactant counterions: thermal properties, self-assembly and photovoltaic performances
Abstract
© 2020 Society of Industrial Chemistry Phosphonium-based polythiophene conjugated polyelectrolytes (CPEs) with three different counterions (dodecylsulfate, octylsulfate and perfluorooctane sulfonate) are synthesized to determine how the nature of the counterion affects the thermal properties, the self-assembly in thin films and the performance as the cathode interfacial layer in polymer solar cells (PSCs). The counterion has a significant effect on the thermal properties of the CPEs, affecting both their glass transition and crystalline behaviour. Grazing-incidence wide-angle X-ray scattering studies also indicate that changing the nature of the counterion influences the microstructural organization in thin films (face-on versus edge-on orientation). The affinity of the CPEs with the underlying photoactive layer in PSCs is highly correlated with the counterion species. Finally, in addition to an increase of the power conversion efficiency of ca 15% when using these CPEs as cathode interfacial layers in PSCs, a higher device stability is noted, compared to a reference device with a calcium interlayer. © 2020 Society of Industrial Chemistry.