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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Docampo, Pablo
Newcastle University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Untangling free carrier and exciton dynamics in layered hybrid perovskites using ultrafast optical and terahertz spectroscopycitations
- 2024The balancing act between high electronic and low ionic transport influenced by perovskite grain boundariescitations
- 2023Untangling free carrier and exciton dynamics in layered hybrid perovskites using ultrafast optical and terahertz spectroscopycitations
- 2022Structure–property investigations in urea tethered iodinated triphenylaminescitations
- 2020A general approach for hysteresis-free, operationally stable metal halide perovskite field-effect transistors.
- 2020A general approach for hysteresis-free, operationally stable metal halide perovskite field-effect transistors.
- 2019Shedding Light on the Moisture Stability of 3D/2D Hybrid Perovskite Heterojunction Thin Filmscitations
- 2018Single-crystal-like optoelectronic-properties of MAPbI3 perovskite polycrystalline thin filmscitations
- 2017Understanding charge transport in lead iodide perovskite thin-film field-effect transistorscitations
- 2016Toward Tailored Film Morphologiescitations
- 2016Hybrid Perovskite/Perovskite Heterojunction Solar Cellscitations
- 2016Synthesis of Perfectly Oriented and Micrometer-Sized MAPbBr(3) Perovskite Crystals for Thin-Film Photovoltaic Applicationscitations
- 2015Reversible Hydration of CH3NH3Pbl3 in Films, Single Crystals, and Solar Cellscitations
- 2015Reversible hydration of CH3NH3PbI3 in films, single crystals, and solar cellscitations
- 2015A Closer Look into Two-Step Perovskite Conversion with X-ray Scatteringcitations
- 2014Bright light-emitting diodes based on organometal halide perovskite.
- 2014Influence of the orientation of methylammonium lead iodide perovskite crystals on solar cell performancecitations
- 2013High-Performance Perovskite-Polymer Hybrid Solar Cells via Electronic Coupling with Fullerene Monolayerscitations
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article
A general approach for hysteresis-free, operationally stable metal halide perovskite field-effect transistors.
Abstract
Despite sustained research, application of lead halide perovskites in field-effect transistors (FETs) has substantial concerns in terms of operational instabilities and hysteresis effects which are linked to its ionic nature. Here, we investigate the mechanism behind these instabilities and demonstrate an effective route to suppress them to realize high-performance perovskite FETs with low hysteresis, high threshold voltage stability (ΔVt < 2 V over 10 hours of continuous operation), and high mobility values >1 cm2/V·s at room temperature. We show that multiple cation incorporation using strain-relieving cations like Cs and cations such as Rb, which act as passivation/crystallization modifying agents, is an effective strategy for reducing vacancy concentration and ion migration in perovskite FETs. Furthermore, we demonstrate that treatment of perovskite films with positive azeotrope solvents that act as Lewis bases (acids) enables a further reduction in defect density and substantial improvement in performance and stability of n-type (p-type) perovskite devices.