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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dyer, Thomas Daniel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2022Fungal colonization and biomineralization for bioprotection of concretecitations
- 2021Potential of Weathered Blast Furnace Slag for use as an Addition in Concretecitations
- 2021Evaluation of low carbon mortar matrices reinforced with natural fibres
- 2019Pozzolanas and pozzolanic materialscitations
- 2017Influence of cement type on resistance to attack from two carboxylic acidscitations
- 2013Interaction of phenolic brownfield contaminants with hydrating Portland cementcitations
- 2011Characterisation of two chemical compounds formed between hydrated portland cement and benzene-1,2-diol (pyrocatechol)citations
- 2011Hydration chemistry of sewage sludge ash used as a cement componentcitations
- 2009Exposure of Portland cement to multiple trace metal loadingscitations
- 2006Influence of solid solutions on chloride leaching from wasteformscitations
- 2004Hydration reactions of cement combinations containing vitrified incinerator fly ashcitations
- 2004Maximising opportunities for recycling glass
- 2003Use of refuse-derived fuel ash as a cement component in mortar
- 2001Chemical reactions of glass cullet used as a cement componentcitations
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article
Influence of solid solutions on chloride leaching from wasteforms
Abstract
NOTE: THE SYMBOLS IN THIS ABSTRACT CANNOT BE DISPLAYED CORRECTLY ON THIS PAGE. PLEASE REFER TO THE ABSTRACT AT THE PUBLISHER'S WEBSITE FOR AN ACCURATE DISPLAY. The hydration product Friedel's salt (Ca4Al2O6Cl2.10H2O) is frequently encountered in wasteforms solidified and stabilised using Portland cement. The ability of Friedel's salt to form solid solutions plays a role in chloride binding in such matrices. This paper addresses one practical example of this influence by examining the immobilisation of chloride ions from municipal solid waste incinerator fly ash in cementitious matrices also comprising Portland cement and fly ash from coal-fired power generation. Measurements of quantities and structural parameters of Friedel's salt in pastes containing incinerator fly ashes show that chloride ion release is lowest when large quantities of chloride-deficient Friedel's salt is generated. However, chloride is more tightly bound elsewhere in the material, probably in calcium silicate hydrate (CSH) gel. The dissolution of Friedel's salt is modelled using a geochemical modelling program capable of dealing with solid solutions. These observations reinforce the need to incorporate variable phase composition in models for predicting leaching from cementitious matrices containing waste materials.