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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Selvakumar, Sermadurai
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article
Polyamides based on the renewable monomer, 1,13-tridecane diamine I: synthesis and characterization of nylon 13,T
Abstract
<jats:p> Nylon 13,T was successfully synthesized, and its chemical composition, thermal properties, crystal structure and moisture absorption were characterized. Melting temperature and glass transition temperature were deter-mined to be 263 and 90°C, respectively, while the equilibrium melting temperature was determined to be 289°C. Characterization of the crystallization kinetics showed that nylon 13,T exhibits very fast crystallization compared with the industrially important nylons, nylon 6 and nylon 6,6. In addition, the moisture absorption of nylon 13,T was dramatically lower than nylon 6 and nylon 6,6, which is consistent with the much lower amide content of nylon 13,T. The crystal structure was determined to be pseudohexagonal. </jats:p>