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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Papatzani, Styliani
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2023Nanomontmorillonite Reinforced Fibre Cements and Nanomontmorillonite-Nanosilica Reinforced Mortarscitations
- 2021Effect of stacking sequence on the performance of hybrid natural/synthetic fiber reinforced polymer composite laminates
- 2020A step by step methodology for building sustainable cementitious matricescitations
- 2019Optimization of low carbon footprint quaternary and quinary (37% fly ash) cementitious nanocomposites with polycarboxylate or aqueous nanosilica particlescitations
- 2019Permeable nanomontmorillonite and fibre reinforced cementitious binderscitations
- 2019ICE Themes Low Carbon Concrete
- 2019From Nanostructural Characterization of Nanoparticles to Performance Assessment of Low Clinker Fibre-Cement Nanohybridscitations
- 2018Pore-structure and microstructural investigation of organomodified/Inorganic nano-montmorillonite cementitious nanocompositescitations
- 2018Pore-structure and microstructural investigation of organomodified/Inorganic nano- montmorillonite cementitious nanocompositescitations
- 2018Lowering cement clinker:citations
- 2018Lowering cement clinker::A thorough, performance based study on the use of nanoparticles of SiO2 or montmorillonite in Portland limestone nanocompositescitations
- 2018Polycarboxylate / nanosilica modified quaternary cement formulations - enhancements and limitationscitations
- 2017Construction, demolition and excavation waste management in EU/Greece and its potential use in concrete
- 2017Inorganic and organomodified nano-montmorillonite dispersions for use as supplementary cementitious materialscitations
- 2016Effect of nanosilica and montmorillonite nanoclay particles on cement hydration and microstructurecitations
- 2015Dispersed Inorganic or Organomodified Montmorillonite Clay Nanoparticles for Blended Portland Cement Pastescitations
- 2015Effects of nanosilica on the calcium silicate hydrates in Portland cement–fly ash systemscitations
- 2015RC structural walls under cyclic loading - Experimental verification of code overestimation of transverse reinforcement reduction potentials
- 2015A comprehensive review of the models on the nanostructure of calcium silicate hydratescitations
- 2014The effect of the addition of nanoparticles of silica on the strength and microstructure of blended Portland cement pastes
- 2014Прочность и микроструктура цементного камня c добавками коллоидного SiO2
Places of action
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article
Effects of nanosilica on the calcium silicate hydrates in Portland cement–fly ash systems
Abstract
Cementitious materials have a complex chemistry and naturally form nanostructures in the hydration process, a network of calcium silicate hydrates. It is considered that nanoparticles such as nanosilica could act as a pozzolanic material as well as a seeding agent for nucleation and acceleration of the formation of the calcium silicate hydrate network. This work evaluates the effect of nanosilica on the calcium silicate hydrate network and microstructure of hardened ternary, quaternary and quinary system Portland cement based pastes. The quinary system, containing Portland cement, limestone, fly ash, microsilica and nanosilica, and ternary combinations (Portland cement, limestone and fly ash) showed mean calcium/silicon atomic ratios of the calcium silicate hydrate gel in the 28 d old hardened paste of 1·2 and 2·3 respectively. Fourier transform infrared spectroscopy results show the presence of the bridging silicate tetrahedra (Q2) characteristic of a peak at around 980 cm−1 and a shoulder at around 1060 cm−1 in the calcium silicate hydrate gel network of the ternary, quaternary and quinary combinations; these bands are thus more pronounced for the nanosilica-enhanced formulations. The sample obtained in the presence of microsilica and nanosilica (quinary combination) showed evidence of a more intricate calcium silicate hydrate gel network (bridging tetrahedra) characteristic of a honeycomb-like structure opposed to the ternary combination (control sample).