Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

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Publications (21/21 displayed)

  • 2023Nanomontmorillonite Reinforced Fibre Cements and Nanomontmorillonite-Nanosilica Reinforced Mortars2citations
  • 2021Effect of stacking sequence on the performance of hybrid natural/synthetic fiber reinforced polymer composite laminatescitations
  • 2020A step by step methodology for building sustainable cementitious matrices13citations
  • 2019Optimization of low carbon footprint quaternary and quinary (37% fly ash) cementitious nanocomposites with polycarboxylate or aqueous nanosilica particles22citations
  • 2019Permeable nanomontmorillonite and fibre reinforced cementitious binders12citations
  • 2019ICE Themes Low Carbon Concretecitations
  • 2019From Nanostructural Characterization of Nanoparticles to Performance Assessment of Low Clinker Fibre-Cement Nanohybrids8citations
  • 2018Pore-structure and microstructural investigation of organomodified/Inorganic nano-montmorillonite cementitious nanocomposites6citations
  • 2018Pore-structure and microstructural investigation of organomodified/Inorganic nano- montmorillonite cementitious nanocomposites6citations
  • 2018Lowering cement clinker:12citations
  • 2018Lowering cement clinker::A thorough, performance based study on the use of nanoparticles of SiO2 or montmorillonite in Portland limestone nanocomposites12citations
  • 2018Polycarboxylate / nanosilica modified quaternary cement formulations - enhancements and limitations14citations
  • 2017Construction, demolition and excavation waste management in EU/Greece and its potential use in concretecitations
  • 2017Inorganic and organomodified nano-montmorillonite dispersions for use as supplementary cementitious materials31citations
  • 2016Effect of nanosilica and montmorillonite nanoclay particles on cement hydration and microstructure93citations
  • 2015Dispersed Inorganic or Organomodified Montmorillonite Clay Nanoparticles for Blended Portland Cement Pastes19citations
  • 2015Effects of nanosilica on the calcium silicate hydrates in Portland cement–fly ash systems30citations
  • 2015RC structural walls under cyclic loading - Experimental verification of code overestimation of transverse reinforcement reduction potentialscitations
  • 2015A comprehensive review of the models on the nanostructure of calcium silicate hydrates153citations
  • 2014The effect of the addition of nanoparticles of silica on the strength and microstructure of blended Portland cement pastescitations
  • 2014Прочность и микроструктура цементного камня c добавками коллоидного SiO2citations

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Paine, Kevin A.
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Siddiquee, Md. Abu Bakar
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Grammatikos, Sotirios
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Das, Subrata Chandra
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Vidakis, Nectarios
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Petousis, Markos
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Paine, Kevin
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Kotsovos, Michael
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Co-Authors (by relevance)

  • Paine, Kevin A.
  • Siddiquee, Md. Abu Bakar
  • Grammatikos, Sotirios
  • Das, Subrata Chandra
  • Vidakis, Nectarios
  • Petousis, Markos
  • Khan, Ruhul A.
  • Koralli, Panagiota
  • Shauddin, S. M.
  • Calabria-Holley, Juliana
  • Adl-Zarrabi, Bijan
  • Paine, Kevin
  • Giannakis, Ioannis
  • Kotsovos, Michael
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article

Effects of nanosilica on the calcium silicate hydrates in Portland cement–fly ash systems

  • Calabria-Holley, Juliana
  • Paine, Kevin A.
  • Papatzani, Styliani
Abstract

Cementitious materials have a complex chemistry and naturally form nanostructures in the hydration process, a network of calcium silicate hydrates. It is considered that nanoparticles such as nanosilica could act as a pozzolanic material as well as a seeding agent for nucleation and acceleration of the formation of the calcium silicate hydrate network. This work evaluates the effect of nanosilica on the calcium silicate hydrate network and microstructure of hardened ternary, quaternary and quinary system Portland cement based pastes. The quinary system, containing Portland cement, limestone, fly ash, microsilica and nanosilica, and ternary combinations (Portland cement, limestone and fly ash) showed mean calcium/silicon atomic ratios of the calcium silicate hydrate gel in the 28 d old hardened paste of 1·2 and 2·3 respectively. Fourier transform infrared spectroscopy results show the presence of the bridging silicate tetrahedra (Q2) characteristic of a peak at around 980 cm−1 and a shoulder at around 1060 cm−1 in the calcium silicate hydrate gel network of the ternary, quaternary and quinary combinations; these bands are thus more pronounced for the nanosilica-enhanced formulations. The sample obtained in the presence of microsilica and nanosilica (quinary combination) showed evidence of a more intricate calcium silicate hydrate gel network (bridging tetrahedra) characteristic of a honeycomb-like structure opposed to the ternary combination (control sample).

Topics
  • nanoparticle
  • impedance spectroscopy
  • microstructure
  • cement
  • Silicon
  • Calcium
  • Fourier transform infrared spectroscopy