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Motta, Antonella |
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document
Composition Influence on the Properties of Titanium-Doped Gamma Iron Oxide Nanoparticles Prepared by Laser Pyrolysis Method
Abstract
<jats:title>Abstract</jats:title><jats:p>The aim of this work is the structural and sensing characterization of titanium-doped gamma iron oxide nanocomposites. These nanopowder materials were synthesized by the laser pyrolysis technique. It is based on the resonance between the emission of a CW CO<jats:sub>2</jats:sub> laser line and the infrared absorption band of a gas (vapour) precursor. Basically, sensitised iron pentacarbonyl and titanium tetrachloride-based mixtures were used as gas-phase reactants. The compositional characterization of the synthesized nanostructures was performed by means of different analytical techniques. Introducing Ti in the Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> network in small quantities (< 1 %) seems to have little influence on titanium doped powder morphology (mean grain size ∼ 5nm) but increases the sensitivity of titanium doped iron oxide nanopowders with more then 20 % relatively to pure maghemite.</jats:p>