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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ohtomo, Akira
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2017Superconductivity in Ti<sub>4</sub>O<sub>7</sub> and γ-Ti<sub>3</sub>O<sub>5</sub> filmscitations
- 2017Epitaxial structure and electronic property of <i>β</i>-Ga<sub>2</sub>O<sub>3</sub> films grown on MgO (100) substrates by pulsed-laser depositioncitations
- 2017Highly oriented epitaxial CaFe<sub>2</sub>O<sub>4</sub> thin films on TiO<sub>2</sub> substrates grown by pulsed-laser depositioncitations
- 2016Fabrication and Characterization of Semiconductor Photoelectrodes with Orientation-Controlled α-Fe<sub>2</sub>O<sub>3</sub> Thin Filmscitations
- 2016Strain-induced metal-insulator transition in <i>t</i><sub>2g</sub> electron system of perovskite titanate Sm<sub>0.5</sub>Ca<sub>0.5</sub>TiO<sub>3</sub> filmsscitations
- 2015Pulsed-laser deposition of superconducting LiTi<sub>2</sub>O<sub>4</sub> ultrathin films
- 2015Direct growth of metallic TiH<sub>2</sub> thin films by pulsed laser depositioncitations
- 2015Conducting Si-doped γ-Ga<sub>2</sub>O<sub>3</sub> epitaxial films grown by pulsed-laser depositioncitations
- 2014Graphoepitaxy of ZnO: novel selection rule of domain formation on nanopatterned glass surface
- 2013Surface and interface engineering of ZnO based heterostructures fabricated by pulsed-laser depositioncitations
- 2013Spontaneous atomic ordering and magnetism in epitaxially stabilized double perovskitescitations
- 2012Epitaxial structures of band-gap-engineered α-(Cr<sub>x</sub>Fe<sub>1-x</sub>)<sub>2</sub>O<sub>3</sub> (0 ≤x≤1) films grown on C-plane sapphirecitations
- 2012Spontaneous atomic ordering and magnetism in epitaxially stabilized double-perovskites
- 2011Ferrimagnetism and spontaneous ordering of transition metals in double perovskite La<sub>2</sub>CrFeO<sub>6</sub> filmscitations
- 2011Magnetic properties of Sr<sub>2</sub>FeTaO<sub>6</sub> double perovskite epitaxially grown by pulsed-laser depositioncitations
- 2010Dimensionality-driven insulator–metal transition in A-site excess non-stoichiometric perovskitescitations
- 2010Optimization of the Growth Conditions for Molecular Beam Epitaxy of Mg<sub>x</sub>Zn<sub>1-x</sub>O (0≤x≤0.12) Films on Zn-Polar ZnO Substratescitations
- 2010Controlled B-site ordering in Sr<SUB>2</SUB>CrReO<SUB>6</SUB> double perovskite films by using pulsed laser interval depositioncitations
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article
Spontaneous atomic ordering and magnetism in epitaxially stabilized double perovskites
Abstract
We have studied the atomic ordering of B-site transition metals and magnetic properties in the pulsed laser deposited films of La<sub>2</sub>CrFeO<sub>6</sub> (LCFO) and La<sub>2</sub>VMnO<sub>6</sub> (LVMO), whose bulk materials are known to be single perovskites with random distribution of the B-site cations. Despite similar ionic characters of constituent transition metals in each compound, the maximum B-site order attained was surprisingly high, ∼90% for LCFO and ∼80% for LVMO, suggesting a significant role of epitaxial stabilization in the spontaneous ordering process. Magnetization and valence state characterizations revealed that the magnetic ground state of both compounds was coincidently ferrimagnetic with saturation magnetization of ∼2 μB per formula unit, unlike those predicted theoretically. In addition, they were found to be insulating with optical band gaps of 1.6 and 0.9 eV for LCFO and LVMO, respectively. Our results present a wide opportunity to explore novel magnetic properties of binary transition metal perovskites upon epitaxial stabilization of the ordered phase.