| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Janßen, Rolf
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Stabilization of porosity in reaction bonded aluminum oxide (RBAO) by coarsening in a reactive atmosphere
- 2022Functionalization of Carbon Electrodes with Nanotitania by Atomic Layer Deposition
- 2019Alumina-doped zirconia submicro-particles : synthesis, thermal stability, and microstructural characterizationcitations
- 2018Photonic materials for high-temperature applications: synthesis and characterization by X-ray ptychographic tomography
- 2017Approximation of mechanical properties of sintered materials with discrete element method
- 2017Approximation of mechanical properties of sintered materials with discrete element method
- 2017Effect of processing route on the microstructure and mechanical properties of hot work tool steel
- 2017Highly porous α-Al 2 O 3 ceramics obtained by sintering atomic layer deposited inverse opals
- 2016High-temperature stable Zirconia particles doped with Yttrium, Lanthanum, and Gadoliniumcitations
- 2015Synthesis and thermal stability of zirconia and yttria-stabilized zirconia microspheres
- 2015Investigation of the phase space in lead-free (K x Na1-x )1-y Li y (Nb1-z Ta z )O3 ferroelectric ceramics
- 2015Yttria-stabilized zirconia microspheres: Novel building blocks for high-temperature photonics
- 2012Ultrasonic characterization of defective porcelain tiles
Places of action
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document
Yttria-stabilized zirconia microspheres: Novel building blocks for high-temperature photonics
Abstract
Zirconia-based ceramics cover a huge variety of applications, including refractories, electro- and bioceramics, fuel cells, catalysts, and many more. For various photonic applications considered for energy systems and heat management, zirconia microspheres are interesting building blocks due to their high refractive index, as well as their chemical and mechanical robustness. However, instabilities caused by thermally-induced phase transitions and grain growth at temperatures above ∼1000 °C preclude high-temperature applications of pure zirconia particles. Here, we present a synthetic route for yttria-stabilized zirconia microparticles with significantly improved thermal stability. With these particles we conducted the first study on their thermal stability as a function of the yttrium content and at temperatures up to 1500 °C. Using X-ray diffraction and scanning electron microscopy, the optimum Y content was determined to be 8-10%, which was marked by stabilization of the tetragonal or cubic phase and significantly attenuated grain growth. Furthermore, with diameters ranging from 2 to 5 μm, the particles covered a size range perfectly suited for photonic applications in the IR spectral range. To demonstrate this, photonic glass coatings were prepared with these particles and their IR reflectivity and microstructural stability was studied after subjecting them to various heating cycles. While heating beyond 1200 °C led to failure and delamination of undoped particle films, films doped with 6 and 10% Y displayed quite stable broadband IR reflection of up to 80% in the wavelength range from 1-5 μm, even after prolonged heating at 1400 °C. A detailed analysis of the X-ray diffraction patterns revealed that prolonged heating at 1400 °C resulted in phase decomposition due to Y segregation into Y-lean and Y-rich domains, confirming the presence of the solute-drag effect.