| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Murshed, Mohammad Mangir
University of Bremen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2024Synthesis and characterization of mullite‐type Sn(Cr1-xVx)BO4: Structural, vibrational, magnetic, and thermal properties
- 2023Ceramic Open Cell Foams Featuring Plasmonic Hybrid Metal Nanoparticles for In Situ SERS Monitoring of Catalytic Reactionscitations
- 2023Gold Nanoparticle‐Coated Bioceramics for Plasmonically Enhanced Molecule Detection via Surface‐Enhanced Raman Scattering
- 2020Crystal structure of the synthetic analogue of iwateite, Na2BaMn(PO4)2: an X-ray powder diffraction and Raman studycitations
- 2016Bi2Fe4O9: Structural changes from nano- to micro-crystalline statecitations
- 2014Synthesis and characterization of mullite-type (Al1-xGax)4B2O9citations
- 2008Gallium substitution in the alumosilicate framework: synthesis and structural studies of hydro sodalitescitations
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article
Gallium substitution in the alumosilicate framework: synthesis and structural studies of hydro sodalites
Abstract
<jats:title>Abstract</jats:title><jats:p>A series of hydro sodalites of composition Na<jats:sub>6</jats:sub>[Al<jats:sub>1−y</jats:sub>Ga<jats:sub>y</jats:sub>SiO<jats:sub>4</jats:sub>]<jats:sub>6</jats:sub>(H<jats:sub>2</jats:sub>O)<jats:sub>8</jats:sub> (0 ≤ <jats:italic>y</jats:italic> ≤ 1) have been prepared from Na<jats:sub>6+x</jats:sub>[Al<jats:sub>1−y</jats:sub>Ga<jats:sub>y</jats:sub>SiO<jats:sub>4</jats:sub>]<jats:sub>6</jats:sub>(OH · H<jats:sub>2</jats:sub>O)<jats:sub>x</jats:sub>(H<jats:sub>2</jats:sub>O)<jats:sub>8−4x</jats:sub> sodalites by NaOH/H<jats:sub>2</jats:sub>O exchange methods carried out in acidic aqueous media. One of the end members (<jats:italic>y</jats:italic> = 1) Na<jats:sub>6</jats:sub>[GaSiO<jats:sub>4</jats:sub>]<jats:sub>6</jats:sub>(H<jats:sub>2</jats:sub>O)<jats:sub>8</jats:sub> is obtained from Na<jats:sub>8</jats:sub>[GaSiO<jats:sub>4</jats:sub>]<jats:sub>6</jats:sub>I<jats:sub>2</jats:sub> by a hydrothermal transformation process. The polycrystalline samples are characterized by Rietveld refinements using X-ray powder diffraction data. The cell parameter fluctuates slightly from the [AlSiO<jats:sub>4</jats:sub>]<jats:sub>6</jats:sub> to the [GaSiO<jats:sub>4</jats:sub>]<jats:sub>6</jats:sub> framework with an average value of 884.8 pm. The occurrence of an almost constant cell parameter has been explained as a combined effect of hydrogen bonding between the oxygen atoms of the entrapped water (or the occluded [Na<jats:sub>3</jats:sub>□(H<jats:sub>2</jats:sub>O)<jats:sub>4</jats:sub>]<jats:sup>3+</jats:sup> complex in the <jats:italic>β</jats:italic>-cage as a whole), and the framework together with six-ring window deformation. During XRD refinements both aluminium and gallium atoms have been converged to a single crystallographic site. The Al/Ga—O bond distance therefore indicates the mean of Al—O and Ga—O distances, which increases with increasing gallium content in the framework. However, the Si—O distance remains almost constant at 162.9 pm at any Ga/Al ratio. The coupled twisting of the (Al,Ga)O<jats:sub>4</jats:sub> and SiO<jats:sub>4</jats:sub> tetrahedra confirms the increase of tilt angles and decrease of six-ring pore dimension upon aluminium replacement by gallium in the framework. Results of <jats:sup>1</jats:sup>H and <jats:sup>29</jats:sup>Si MAS NMR as well as FTIR spectroscopy are also discussed in terms of successive gallium incorporation in the alumosilicate hydro sodalite frameworks.</jats:p>