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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mahmood, Khalid
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2023Biologically potent organotin(<scp>iv</scp>) complexes of <i>N</i>-acetylated β-amino acids with spectroscopic, X-ray powder diffraction and molecular docking studiescitations
- 2023Identifying primary and secondary MLH1 epimutation carriers displaying low-level constitutional MLH1 methylation using droplet digital PCR and genome-wide DNA methylation profiling of colorectal cancerscitations
- 2022Synthesis of poly (N-isopropyl acrylamide-co-2-acrylamido methylpropane sulfonic acid) hydrogel containing copper and nickel nanoparticles with easy recycling and efficient catalytic potentialcitations
- 2020An Experimental Study of Bond Behavior of Micro Steel Fibers Added Self-compacting Concrete with Steel Reinforcementcitations
- 2013Direct laser deposition with different types of 316L steel particlecitations
- 2012Laser surface modification using Inconel 617 machining swarf as coating materialcitations
- 2012Mechanical, swelling, and thermal aging properties of marble sludge-natural rubber composites
- 2011Material-efficient laser cladding for corrosion resistance
- 2011Laser metal deposition of steel components using machining waste as build material
- 2011Laser surface cladding of Inconel 617 chips on mild steel
- 2011Innovative reconsolidation of carbon steel machining swarf by laser metal depositioncitations
- 2010Energy conservation by efficiently utilizing machining waste
- 2010Laser direct deposition of carbon steel machining waste
Places of action
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article
Synthesis of poly (N-isopropyl acrylamide-co-2-acrylamido methylpropane sulfonic acid) hydrogel containing copper and nickel nanoparticles with easy recycling and efficient catalytic potential
Abstract
<jats:title>Abstract</jats:title><jats:p>Poly(N-isopropyl acrylamide-co-2-acrylamido methyl propane sulfonic acid) hydrogel was prepared and used as matrix for the fabrication of nickel and copper nanoparticles. Nickel and copper nanoparticles were fabricated via <jats:italic>in situ</jats:italic> reduction of Ni (II) and Cu (II) ions within the hydrogel matrix. The manufactured hydrogel and its corresponding composites with Ni and Cu nanoparticles were characterized by FTIR, XRD, EDX, TEM, and TGA. Thermal stability of hydrogel was found to be increased upon fabricating with metal nanoparticles. The hydrogel showed ability to absorb water 63 times of its weight in dried form. The Ni and Cu nanoparticles were observed to be well dispersed, spherical in shape and most of them were having diameters in the range of 12.5 to 38.8 nm and 58 to 102 nm, respectively. The as-prepared hydrogel-nickel and hydrogel-Cu nanocomposite were used as catalysts for the reduction of a toxic pollutant 4-nitrophenol. At 25 °C, the reduction of 4-NP was found to proceed with apparent rate constant (<jats:italic>k</jats:italic><jats:sub>app</jats:sub>) of 0.107 and 0.122 min<jats:sup>−1</jats:sup> in the presence of composite containing Ni and Cu nanoparticles, respectively. However, <jats:italic>k</jats:italic><jats:sub>app</jats:sub> was increased with corresponding increase in temperature and its maximum value was found to be 0.815 min<jats:sup>−1</jats:sup> at 88 °C with catalyst containing Ni nanoparticles. The formation of well dispersed Ni and Cu nanoparticles in the prepared hydrogel reflected that this hydrogel system can act as efficient stabilizing agent along with acting as a reactor medium. Recycling potential of catalysts was studied for five successive cycles.</jats:p>