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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Coelho Junqueira, João Ricardo
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Combinatorial screening of electronic and geometric effects in compositionally complex solid solutions toward a rational design of electrocatalysts
- 2020High-throughput exploration of metal vanadate thin-film systems (M-V-O, M = Cu, Ag, W, Cr, Co, Fe) for solar water splittingcitations
- 2020Structural and photoelectrochemical properties in the thin film system Cu-Fe-V-O and its ternary subsystems Fe-V-O and Cu -V-Ocitations
- 2020High-throughput characterization of Ag–V–O nanostructured thin-film materials libraries for photoelectrochemical solar water splittingcitations
- 2019Discovery of solar water splitting materials in multinary metal oxide systems by combinatorial synthesis and high-throughput characterization of thin-film materials libraries
- 2019High-Throughput Characterization of Structural and Photoelectrochemical Properties of a Bi–Mo–W–O Thin-Film Materials Librarycitations
- 2018Investigation of Vanadate-metal-oxide thin film systems for solar water splitting
- 2018Combinatorial fabrication and high-throughput characterization of thin film metal oxide libraries for solar water splitting
- 2018Combinatorial synthesis and high-throughput characterization of Fe-V-O thin-film materials libraries for solar water splittingcitations
Places of action
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article
High-Throughput Characterization of Structural and Photoelectrochemical Properties of a Bi–Mo–W–O Thin-Film Materials Library
Abstract
<jats:title>Abstract</jats:title> <jats:p>A Bi–W–Mo–O thin-film materials library was fabricated by combinatorial reactive magnetron sputtering. The composition spread was investigated using high-throughput methods to determine crystalline phases, composition, morphology, optical properties, and photoelectrochemical performance. The aurivillius phase (Bi<jats:sub>2</jats:sub>O<jats:sub>2</jats:sub>)<jats:sup>2+</jats:sup> (Bi<jats:sub>M</jats:sub>(W<jats:sub>1−N</jats:sub>Mo<jats:sub>N</jats:sub>)<jats:sub>M−1</jats:sub>O<jats:sub>3M+1</jats:sub>)<jats:sup>2−</jats:sup> is the predominantly observed crystal structure, indicating that the thin films in the library are solid solutions. With increasing amounts of Mo ≙ 7–22% the diffraction peak at 2θ = 28° ≙ [131] shifts due to lattice distortion, the photoelectrochemical activity is increasing up to a wavelength of 460 nm with an incident photon to current efficiency (IPCE) of 4.5%, and the bandgap decreases. A maximum photocurrent density of 31 μA/cm<jats:sup>2</jats:sup> was measured for Bi<jats:sub>31</jats:sub>W<jats:sub>62</jats:sub>Mo<jats:sub>7</jats:sub>O<jats:sub>z</jats:sub> at a bias potential of 1.23 V vs. RHE (0.1 M Na<jats:sub>2</jats:sub>SO<jats:sub>4</jats:sub>).</jats:p>