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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Janka, Oliver
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2024Ferrocene-Modified Polyacrylonitrile-Containing Block Copolymers as Preceramic Materials
- 2024On the Ytterbium Valence and the Physical Properties in Selected Intermetallic Phases
- 2024Nominal CaAl2Pt2 and Ca2Al3Pt – two new Intermetallic Compounds in the Ternary System Ca−Al−Pt
- 2024Synthesis, magnetic and NMR spectroscopic properties of the MAl5Pt3 series (M = Ca, Y, La–Nd, Sm–Er)†citations
- 2023Eu4Al13Pt9 – a coloring variant of the Ho4Ir13Ge9 type structurecitations
- 2023Single‐Source Precursors for the Chemical Vapor Deposition of Iron Germanides
- 2023Raman and NMR spectroscopic and theoretical investigations of the cubic laves-phases REAl2 (RE = Sc, Y, La, Yb, Lu)citations
- 2023Self-Assembly of Polymer-Modified FePt Magnetic Nanoparticles and Block Copolymerscitations
- 2023On the RE2TiAl3 (RE = Y, Gd–Tm, Lu) Series : The First Aluminum Representatives of the Rhombohedral Mg2Ni3Si Type Structure
- 2023MAl4Ir2 (M = Ca, Sr, Eu): superstructures of the KAu4In2 typecitations
- 2023Trivalent europium – a scarce case in intermetallicscitations
- 2023Crystalline Carbosilane-Based Block Copolymers: Synthesis by Anionic Polymerization and Morphology Evaluation in the Bulk Statecitations
- 2022Crystalline Carbosilane‐Based Block Copolymers: Synthesis by Anionic Polymerization and Morphology Evaluation in the Bulk State
- 2022MAl4Ir2 (M = Ca, Sr, Eu) : superstructures of the KAu4In2 type
- 2020Squares of gold atoms and linear infinite chains of Cd atoms as building units in the intermetallic phases REAu4Cd2 (RE=La–Nd, Sm) with YbAl4Mo2-type structurecitations
- 2017Microstructure investigations of Yb- and Bi-doped Mg 2 Si prepared from metal hydrides for thermoelectric applicationscitations
- 2017Hydrogenation-induced cerium valence change in CeNiZncitations
- 2016Cerium intermetallics CeTX – review IIIcitations
- 2016Cerium intermetallics with TiNiSi-type structurecitations
- 2014The gallium intermetallics REPdGa3 (RE = La, Ce, Pr, Nd, Sm, Eu) with SrPdGa3-type structurecitations
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article
Squares of gold atoms and linear infinite chains of Cd atoms as building units in the intermetallic phases REAu4Cd2 (RE=La–Nd, Sm) with YbAl4Mo2-type structure
Abstract
<jats:title>Abstract</jats:title><jats:p>The gold-rich intermetallic compounds <jats:italic>RE</jats:italic>Au<jats:sub>4</jats:sub>Cd<jats:sub>2</jats:sub> (<jats:italic>RE</jats:italic> = La–Nd, Sm) were synthesized from the elements in sealed tantalum ampoules. Their characterization by X-ray powder and single crystal data confirmed the tetragonal YbAl<jats:sub>4</jats:sub>Mo<jats:sub>2</jats:sub> type, space group <jats:italic>I</jats:italic>4/<jats:italic>mmm</jats:italic>. The basic building units are Au<jats:sub>4</jats:sub> squares (278 pm Au–Au in CeAu<jats:sub>4</jats:sub>Cd<jats:sub>2</jats:sub>) and infinite linear cadmium chains (275 pm Cd–Cd in CeAu<jats:sub>4</jats:sub>Cd<jats:sub>2</jats:sub>). We exemplarily studied the solid solution CeAu<jats:sub>4+</jats:sub><jats:italic><jats:sub>x</jats:sub></jats:italic>Cd<jats:sub>2−</jats:sub><jats:italic><jats:sub>x</jats:sub></jats:italic> for <jats:italic>x</jats:italic> = 0–1 up to CeAu<jats:sub>5</jats:sub>Cd. Electron diffraction patterns on a CeAu<jats:sub>5</jats:sub>Cd sample confirm the single crystal data. They give no hint for complete gold-cadmium ordering. Temperature-dependent magnetic susceptibility measurements of CeAu<jats:sub>4</jats:sub>Cd<jats:sub>2</jats:sub>, CeAu<jats:sub>5</jats:sub>Cd, PrAu<jats:sub>4</jats:sub>Cd<jats:sub>2</jats:sub> and NdAu<jats:sub>4</jats:sub>Cd<jats:sub>2</jats:sub> show stable trivalent rare earth ions and give no hint for magnetic ordering above 3 K.</jats:p>