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Zaremba, Vasyl
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article
Phase equilibrium in the Gd-Ni-In system at 870 K
Abstract
<jats:title>Abstract</jats:title><jats:p>The isothermal section of the Gd-Ni-In system at <jats:italic>T</jats:italic> = 870 K was constructed by means of X-ray powder diffraction and EDX analyses. Thirteen ternary compounds, namely GdNi<jats:sub>9</jats:sub>In<jats:sub>2</jats:sub> (YNi<jats:sub>9</jats:sub>In<jats:sub>2</jats:sub> type), Gd<jats:sub>1−1.22</jats:sub>Ni<jats:sub>4</jats:sub>In<jats:sub>1-0.78</jats:sub> (MgCu<jats:sub>4</jats:sub>Sn type), GdNiIn<jats:sub>2</jats:sub> (MgCuAl<jats:sub>2</jats:sub> type), Gd<jats:sub>4</jats:sub>Ni<jats:sub>11</jats:sub>In<jats:sub>20</jats:sub> (U<jats:sub>4</jats:sub>Ni<jats:sub>11</jats:sub>Ga<jats:sub>20</jats:sub> type), GdNi<jats:sub>1.0-0.7</jats:sub>In<jats:sub>1.0-1.3</jats:sub> (ZrNiAl type), Gd<jats:sub>2</jats:sub>Ni<jats:sub>2</jats:sub>In (Mn<jats:sub>2</jats:sub>AlB<jats:sub>2</jats:sub> type), Gd<jats:sub>2</jats:sub>Ni<jats:sub>1.78</jats:sub>In (Mo<jats:sub>2</jats:sub>FeB<jats:sub>2</jats:sub> type), Gd<jats:sub>11</jats:sub>Ni<jats:sub>4</jats:sub>In<jats:sub>9</jats:sub> (Nd<jats:sub>11</jats:sub>Pd<jats:sub>4</jats:sub>In<jats:sub>9</jats:sub> type), Gd<jats:sub>12</jats:sub>Ni<jats:sub>6</jats:sub>In (Sm<jats:sub>12</jats:sub>Ni<jats:sub>6</jats:sub>In type), Gd<jats:sub>6</jats:sub>Ni<jats:sub>2.39</jats:sub>In<jats:sub>0.61</jats:sub> (Ho<jats:sub>6</jats:sub>Co<jats:sub>2</jats:sub>Ga type), Gd<jats:sub>14</jats:sub>Ni<jats:sub>3.29</jats:sub>In<jats:sub>2.71</jats:sub> (Lu<jats:sub>14</jats:sub>Co<jats:sub>3</jats:sub>In<jats:sub>3</jats:sub> type), Gd<jats:sub>3</jats:sub>Ni<jats:sub>0.05</jats:sub>In<jats:sub>0.95</jats:sub> (AuCu<jats:sub>3</jats:sub> type) and ~Gd<jats:sub>6</jats:sub>Ni<jats:sub>2</jats:sub>In exist in the Gd-Ni-In system at this temperature. The substitution of Ni for In was observed for GdNi<jats:sub>1.0-0.7</jats:sub>In<jats:sub>1.0-1.3</jats:sub> and of In for Gd for Gd<jats:sub>1-1.22</jats:sub>Ni<jats:sub>4</jats:sub>In<jats:sub>1-0.78</jats:sub>. Besides, Gd can enter the structure of NiIn (CoSn type) leading to a solid solution Gd<jats:sub>0-0.14</jats:sub>NiIn<jats:sub>1-0.98</jats:sub>.</jats:p>