| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Heymann, Gunter
Universität Innsbruck
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Tb2Co(B2O5)2 and Tb2Cu(B2O5)2 – two new borates with gadolinite-type structurescitations
- 2023Crystal structures and luminescence properties of Li6MN4:Ce3+ (M = Mo, W)
- 2019Serendipitous formation and characterization of K2[Pd(NO3)4]·2HNO3
- 2018Synthesis and characterization of the new tin borate SnB8O11(OH)4citations
- 2017The high-pressure phase of CePtAlcitations
- 2016Synthesis and characterization of the novel rare earth orthophosphates Y0.5Er0.5PO4 and Y0.5Yb0.5PO4citations
- 2016Hydrothermal synthesis of a new lead(II) borate (Pb4O)Pb2B6O14-IIcitations
- 2013Ce4Ag3Ge4O0.5 - chains of oxygen-centered OCe2Ce2/2] tetrahedra embedded in a CeAg3Ge4] intermetallic matrixcitations
- 2005High-Pressure Synthesis of a Gallium Oxonitride with a Spinel-Type Structurecitations
Places of action
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article
Serendipitous formation and characterization of K2[Pd(NO3)4]·2HNO3
Abstract
<jats:title>Abstract</jats:title><jats:p>A potassium tetranitratopalladate(II) with the composition K<jats:sub>2</jats:sub>[Pd(NO<jats:sub>3</jats:sub>)<jats:sub>4</jats:sub>] · 2HNO<jats:sub>3</jats:sub> was synthesized by a simple solvothermal process in a glass ampoule. The new compound crystallizes in the monoclinic space group <jats:italic>P</jats:italic>2<jats:sub>1</jats:sub><jats:italic>/c</jats:italic> (no. 14) with the lattice parameters <jats:italic>a</jats:italic> = 1017.15(4), <jats:italic>b</jats:italic> = 892.94(3), <jats:italic>c</jats:italic> = 880.55(3) Å, and <jats:italic>β</jats:italic> = 98.13(1)° (<jats:italic>Z</jats:italic> = 2). The crystal structure of K<jats:sub>2</jats:sub>[Pd(NO<jats:sub>3</jats:sub>)<jats:sub>4</jats:sub>] · 2HNO<jats:sub>3</jats:sub> reveals isolated complex [Pd(NO<jats:sub>3</jats:sub>)<jats:sub>4</jats:sub>]<jats:sup>2−</jats:sup> anions, which are surrounded by eight potassium cations and four HNO<jats:sub>3</jats:sub> molecules. The complex anions and the cations are associated in layers which are separated by HNO<jats:sub>3</jats:sub> molecules. K<jats:sub>2</jats:sub>[Pd(NO<jats:sub>3</jats:sub>)<jats:sub>4</jats:sub>] · 2HNO<jats:sub>3</jats:sub> can thus be regarded as a HNO<jats:sub>3</jats:sub> intercalation variant of <jats:italic>β</jats:italic>-K<jats:sub>2</jats:sub>[Pd(NO<jats:sub>3</jats:sub>)<jats:sub>4</jats:sub>]. The characterization is based on single-crystal X-ray and powder X-ray diffraction.</jats:p>