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Daszkiewicz, Marek
in Cooperation with on an Cooperation-Score of 37%
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article
Crystal structure of Sc<sub>3</sub>Co<sub>1.64</sub>In<sub>4</sub> and Sc<sub>10</sub>Co<sub>9</sub>In<sub>20</sub> from single-crystal data
Abstract
<jats:title>Abstract</jats:title><jats:p>Two compounds in the Sc-Co-In system were obtained by arc-melting of the pure metals and their crystal structures have been determined using single crystal X-ray diffraction data. The structure of Sc<jats:sub>3</jats:sub>Co<jats:sub>1.64</jats:sub>In<jats:sub>4</jats:sub> (space group <jats:italic>P</jats:italic>6̅, <jats:italic>а</jats:italic>=7.6702(5), <jats:italic>c</jats:italic>=3.3595(2) Å, <jats:italic>Z</jats:italic>=1, <jats:italic>R</jats:italic><jats:sub>1</jats:sub>=0.0160, <jats:italic>wR</jats:italic><jats:sub>2</jats:sub>=0.0301) belongs to the Lu<jats:sub>3</jats:sub>Co<jats:sub>2−</jats:sub><jats:italic><jats:sub>x</jats:sub></jats:italic>In<jats:sub>4</jats:sub> type structure, which is closely related to the ZrNiAl and Lu<jats:sub>3</jats:sub>CoGa<jats:sub>5</jats:sub> types. The structure of Sc<jats:sub>10</jats:sub>Co<jats:sub>9</jats:sub>In<jats:sub>20</jats:sub> (space group <jats:italic>P</jats:italic>4<jats:italic>/nmm</jats:italic>, <jats:italic>а</jats:italic>=12.8331(1), <jats:italic>c</jats:italic>=9.0226(1) Å, <jats:italic>Z</jats:italic>=2, <jats:italic>R</jats:italic><jats:sub>1</jats:sub>=0.0203, <jats:italic>wR</jats:italic><jats:sub>2</jats:sub>=0.0465) belongs to the Ho<jats:sub>10</jats:sub>Ni<jats:sub>9</jats:sub>In<jats:sub>20</jats:sub> type, which is closely related to HfNiGa<jats:sub>2</jats:sub>.</jats:p>