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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Kelly, Nicola D.
University of Oxford
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2022Crystal structure and specific heat of calcium lanthanide oxyborates Ca4LnO(BO3)3citations
- 2021Impact of Orientational Glass Formation and Local Strain on Photo-Induced Halide Segregation in Hybrid Metal-Halide Perovskites
- 2021Impact of Orientational Glass Formation and Local Strain on Photo-Induced Halide Segregation in Hybrid Metal-Halide Perovskitescitations
- 2021Impact of Orientational Glass Formation and Local Strain on Photo-Induced Halide Segregation in Hybrid Metal-Halide Perovskitescitations
- 2021Impact of Orientational Glass Formation and Local Strain on Photo-Induced Halide Segregation in Hybrid Metal-Halide Perovskites.
- 2020Comparison of the ionic conductivity properties of microporous and mesoporous MOFs infiltrated with a Na-ion containing IL mixture.
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article
Crystal structure and specific heat of calcium lanthanide oxyborates Ca4LnO(BO3)3
Abstract
Calcium lanthanide oxyborates Ca4LnO(BO3)3 are of interest for their optical and electromechanical properties. Their crystal structure has been well characterised using powder and single-crystal X-ray diffraction but there remains some disagreement regarding cation ordering in these compounds. In this study, combined X-ray and neutron powder diffraction was employed to study the cation distribution and obtain accurate boron and oxygen atomic coordinates for six Ca4LnO(BO3)3 compounds (Ln = Pr, Nd, Tb, Ho, Er, Yb) at room temperature and one (Ln = Tb) at 50 K and 1.5 K. All compounds adopt the previously reported monoclinic structure with space group ᵃ6ᵅA. The Ln3+ ions are disordered over two of the three metal sites, with the extent of disorder increasing across the lanthanide series with decreasing ionic radius. Low-temperature neutron data for Ca4TbO(BO3)3 showed a decrease in paramagnetic scattering on cooling but no obvious magnetic Bragg or diffuse scattering at the lowest temperature of 1.5 K. We report specific heat data at cryogenic temperatures for eight Ca4LnO(BO3)3 compounds and relate the magnetic properties of these compounds to their structural behaviour. ; Institut Laue-Langevin (ILL) EP/R513180/1, EP/M000524/1, EP/T028580/1