| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Yahia, Hamdi Ben
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO2 and Methane Capturecitations
- 2022Cyclohexylammonium Hexaisothiocyanatonickelate(II) Dihydrate as a Single-Source Precursor for High Surface Area Nickel Oxide and Sulfide Nanocrystalscitations
- 2016Crystal structure of the alluaudite Ag<sub>2</sub>Mn<sub>3</sub>(VO<sub>4</sub>)<sub>3</sub>citations
- 2014The new disordered triplite polymorph of Co<sub>2</sub>[PO<sub>4</sub>]F
- 2011The Solid Solution Lu<sub>2–x</sub>Sc<sub>x</sub>SiO<sub>5</sub>citations
- 2010Condensed [OPr<sub>4</sub>]<sup>10+</sup> and Discrete [AsO<sub>3</sub>]<sup>3–Ψ1</sup>-Tetrahedra in Pr<sub>5</sub>O<sub>4</sub>Cl[AsO<sub>3</sub>]<sub>2</sub>citations
- 2010Intermetallic Magnesium Compounds RE<sub>2</sub>Ni<sub>2</sub>Mg<sub>3</sub> (RE =Gd, Dy–Tm, Lu) with Tb<sub>2</sub>Ni<sub>2</sub>Mg<sub>3</sub>-type Structurecitations
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article
The new disordered triplite polymorph of Co<sub>2</sub>[PO<sub>4</sub>]F
Abstract
<jats:title>Abstract</jats:title><jats:p>The new polymorph of Co<jats:sub>2</jats:sub>[PO<jats:sub>4</jats:sub>]F has been synthesized by a hydrothermal route. Its crystal structure was determined from single-crystal X-ray diffraction data. Co<jats:sub>2</jats:sub>[PO<jats:sub>4</jats:sub>]F crystallizes with the triplite-type structure, space group <jats:italic>C</jats:italic>2<jats:italic>/c</jats:italic>, <jats:italic>a</jats:italic>=12.856(2), <jats:italic>b</jats:italic>=6.4369(10), <jats:italic>c</jats:italic>=9.6742(16) Å, <jats:italic>β</jats:italic>=117.40(1)°, <jats:italic>V</jats:italic>=710.7(2) Å<jats:sup>3</jats:sup> and <jats:italic>Z</jats:italic>=8. The structure consists of a 3D-framework buildup of condensed PO<jats:sub>4</jats:sub> tetrahedra, and cobalt(II) polyhedra which form chains running along the [101] and [010] directions. The coordination of the cobalt cations and the connectivity between the cobalt polyhedra are not well defined due to the disorder of the fluoride anions which form zigzag chains along [001]. The theoretical ordering of the fluoride anions led to two different structural models, very similar to the triplite <jats:italic>Cc-</jats:italic>CoFe[PO<jats:sub>4</jats:sub>]F and the triploidite <jats:italic>P</jats:italic>2<jats:sub>1</jats:sub>/<jats:italic>c</jats:italic>-Co<jats:sub>2</jats:sub>[PO<jats:sub>4</jats:sub>]F, and in which the cobalt atoms are five and six coordinated.</jats:p>